Proving Orthogonal Functions: Integral of $\phi_{m}^* \phi_{n}$

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SUMMARY

The discussion centers on proving the orthogonality of wave functions in quantum mechanics, specifically through the integral of the product of two wave functions, $\phi_{m}^*$ and $\phi_{n}$. The key equation derived is \(-\frac{\hbar^2}{2m} \frac{d}{dx} \left[ \phi_{m}^* \frac{d \phi_{n}}{dx} - \phi_{n} \frac{d \phi_{m}^*}{dx}\right] = (E_{m} - E_{n}) \phi_{m}^* \phi_{n}\). By integrating this expression over all space and applying the boundary condition that both wave functions vanish at infinity, it is established that \(\int_{-\infty}^{\infty} \phi_{m}^*(x) \phi_{n}(x) dx = 0\) if \(E_{m} \neq E_{n}\).

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly wave functions.
  • Familiarity with the concept of orthogonality in functional analysis.
  • Knowledge of integration techniques in calculus.
  • Basic understanding of the Schrödinger equation and its implications.
NEXT STEPS
  • Study the properties of wave functions in quantum mechanics.
  • Learn about the implications of orthogonality in quantum states.
  • Explore the derivation and applications of the Schrödinger equation.
  • Investigate boundary conditions in quantum systems and their effects on wave functions.
USEFUL FOR

Students and professionals in physics, particularly those focusing on quantum mechanics, as well as educators teaching the principles of wave functions and their orthogonality.

stunner5000pt
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In the first hald of this question it was proven that

[tex]-\frac{\hbar^2}{2m} \frac{d}{dx} \left[ \phi_{m}^* \frac{d \phi_{n}}{dx} - \phi_{n} \frac{d \phi_{m}^*}{dx}\right] = (E_{m} - E_{n}) \phi_{m}^* \phi_{n}[/tex]

By integrating over x and by assuming taht Phi n and Phi m are zero are x = +/- infinity show that

[tex]\int_{-infty}^{infty} \phi_{m}^*(x) \phi_{n}(x) dx = 0[/tex] if Em is not En

so for this do i simply integrate that above expression wrt x?? is it really that simple?
 
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I'd say so.
 

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