QM: Angular Momentum - Values, Eigenvalues & Ground State Difference

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Homework Help Overview

The discussion revolves around a quantum mechanics problem involving angular momentum and energy eigenvalues for a system represented by a Hamiltonian. The original poster explores the implications of angular momentum values and their relationship to energy states in a cylindrical particle system.

Discussion Character

  • Conceptual clarification, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • The original poster attempts to determine possible values for angular momentum and energy eigenvalues by solving eigenvalue equations and applying boundary conditions. They express confusion regarding the relationship between angular momentum eigenstates and energy measurements, particularly in the context of quantum mechanics principles.

Discussion Status

Some participants suggest that the commutation relation between the angular momentum operator and the Hamiltonian may clarify the relationship between their eigenstates. They note that since the Hamiltonian is based on the square of the angular momentum operator, the eigenfunctions of angular momentum are also energy eigenfunctions, which may resolve the original poster's dilemma.

Contextual Notes

Participants are considering the implications of boundary conditions and the nature of eigenstates in quantum mechanics, particularly in relation to the non-degenerate spectrum of angular momentum. There is an ongoing exploration of assumptions regarding the relationship between angular momentum and energy eigenvalues.

quasar987
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The question:

I am given a system (a cylinder made of particles), and its hamiltonian:

[tex]\hat{H} = \frac{L_z^2}{2MR^2} , \ \ \ \ \ \ L_z = -ih\frac{\partial}{\partial \phi}[/tex]

a) What are the possible values for the angular momentum?

b) What are the eigenvalues of the energy?

c) What is the difference btw the energy of the ground state of angular momentum 0 and the first rotational state?


My dilema: The answer to a) is found by solving the eigenvalue equation for the operator L_z and applying the boundary condition that a change of 2pi in the argument of the wave function must not change its value. I find that the possible values are [itex]L_z = n\hbar[/itex], where n is an integer (I saw no reason not to allow negative n).

The answer to b) is found in the same way: first solve the eigenvalue equation, then apply the same boundary condition. I find

[tex]E_k = \frac{\hbar^2k^2}{2MR^2}[/tex]

where k is an integer but not 0.

But question c) seems contradictory with the principles of QM. Here's why: If I say that the angular momentum is 0. then it means that the wave function is collapsed to an eigenfunction corresponding to the eigenvalue L = 0. And if, after that, I want the energy, then for each eigen energy, I can only assert that there is a cerain probability that my measurement will yield each of these energies. This probability is the square of the norm of the coefficient a_n associated with the n-th energy eigenfunction in the expansion of the wave function (in this case, the angular momentum eigenfunction of eigenvalue L = 0) in terms of the energy eigenfunctions.

So there is no energy associated with a given angular momentum eigenfunction, so I cannot compute a difference.

Where's the problem? Thx!
 
Last edited:
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Unless L_z and H commute! In this case they have the same eigenfunction I think... but I'd have made a mistake in solving the eigenvalue equations then... got to find that commutation relation, brb.
 
Have you actually checked the eigenstates of the angular momentum are also energy eigenstates?

In general, you're right, but in this case H is basically the square of L_z, so an eigenfunction of L_z will also be an eigenfunction of H. The energy associated with it is ofcourse simply the square of the angular momentum divided by 2MR^2 (moment of inertia).

Another way to see this is that H and L_z trivially commute, so they have a common basis of eigenstates. Since the spectrum of L_z is nondegenerate, the set of eigenstates you found is the eigenbasis common to H and L_z.

EDIT: AH, you had the lightbulb flashing moment while I was posting :-p
 
yes, they do trivially commute.. :P
 

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