Quadratic Stark Effect - Perturbation Theory

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SUMMARY

The discussion focuses on the Quadratic Stark Effect and its analysis through perturbation theory. Key points include the parity operator's implications on states, specifically that ##[H_0,P] = 0## and ##H_1P = -PH_1##, which arises from the nature of the perturbation ##H_1 \propto z##. Additionally, the representation of operators as matrices and the significance of matrix elements between parity states are explored, particularly regarding why diagonal matrix elements vanish.

PREREQUISITES
  • Understanding of quantum mechanics, specifically perturbation theory.
  • Familiarity with parity operators and their properties.
  • Knowledge of matrix representations of quantum operators.
  • Experience with the Quadratic Stark Effect and its implications in atomic physics.
NEXT STEPS
  • Study the implications of parity operators in quantum mechanics.
  • Learn about the mathematical formulation of perturbation theory in quantum systems.
  • Explore the derivation and applications of the Quadratic Stark Effect in atomic physics.
  • Investigate the significance of matrix elements in quantum mechanics, particularly in relation to symmetry properties.
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Students and researchers in quantum mechanics, particularly those focusing on atomic physics, perturbation theory, and the analysis of the Quadratic Stark Effect.

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Homework Statement



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Homework Equations


The Attempt at a Solution



With a parity operator, Px = -x implies x has odd parity while Px = x implies x has even parity.

Things that puzzle me

1. Why is ##[H_0,P] = 0## and ##H_1P = -PH_1##? Is it because ##H_1 \propto z## so ##Pz = -z##? Then shouldn't it be ##PH_1 = -H_1##?

2. For any operator R, it is represented by a matrix ##R_{ij} = <i|R|j>##. In this case is the operator in question ##PH_1 + H_1P##? What does 'matrix element between two parity states' mean? From what I see, ##<n'l'm'p'|PH_1 + H_1P|nlmp>## is simply the addition of two matrices, one corresponding to ##PH_1## and another ##H_1P##. Which has odd/even parity and why?

3. Why do all diagonal matrix elements vanish?
 
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Would appreciate clarifying doubts on the 3 points above!
 

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