Quadratic Stark Effect - Perturbation Theory

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Homework Help Overview

The discussion revolves around the Quadratic Stark Effect and its analysis through perturbation theory, focusing on the properties of parity operators and their implications on matrix elements in quantum mechanics.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • The original poster attempts to understand the commutation relations involving the Hamiltonian and parity operator, questioning the implications of these relations on the parity of states. They also seek clarification on the representation of operators as matrices and the significance of matrix elements between parity states. Additionally, they inquire about the conditions under which diagonal matrix elements vanish.

Discussion Status

The discussion is ongoing, with participants exploring various interpretations of the mathematical properties related to the problem. Some participants have expressed a desire for clarification on specific points raised by the original poster, indicating a collaborative effort to deepen understanding.

Contextual Notes

The original poster has posed multiple questions that suggest a need for further exploration of the underlying principles of quantum mechanics, particularly in the context of perturbation theory and parity. There may be constraints related to the homework guidelines that limit the scope of provided assistance.

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Homework Statement



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Homework Equations


The Attempt at a Solution



With a parity operator, Px = -x implies x has odd parity while Px = x implies x has even parity.

Things that puzzle me

1. Why is ##[H_0,P] = 0## and ##H_1P = -PH_1##? Is it because ##H_1 \propto z## so ##Pz = -z##? Then shouldn't it be ##PH_1 = -H_1##?

2. For any operator R, it is represented by a matrix ##R_{ij} = <i|R|j>##. In this case is the operator in question ##PH_1 + H_1P##? What does 'matrix element between two parity states' mean? From what I see, ##<n'l'm'p'|PH_1 + H_1P|nlmp>## is simply the addition of two matrices, one corresponding to ##PH_1## and another ##H_1P##. Which has odd/even parity and why?

3. Why do all diagonal matrix elements vanish?
 
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Would appreciate clarifying doubts on the 3 points above!
 

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