Quadratic Stark Effect - Perturbation Theory

Join the discussion
Registration is free. Ask a follow-up in this thread, or start your own.
5 replies · 3K views
unscientific
Messages
1,728
Reaction score
13

Homework Statement



2u9nwk0.png


Homework Equations


The Attempt at a Solution



With a parity operator, Px = -x implies x has odd parity while Px = x implies x has even parity.

Things that puzzle me

1. Why is ##[H_0,P] = 0## and ##H_1P = -PH_1##? Is it because ##H_1 \propto z## so ##Pz = -z##? Then shouldn't it be ##PH_1 = -H_1##?

2. For any operator R, it is represented by a matrix ##R_{ij} = <i|R|j>##. In this case is the operator in question ##PH_1 + H_1P##? What does 'matrix element between two parity states' mean? From what I see, ##<n'l'm'p'|PH_1 + H_1P|nlmp>## is simply the addition of two matrices, one corresponding to ##PH_1## and another ##H_1P##. Which has odd/even parity and why?

3. Why do all diagonal matrix elements vanish?
 
Physics news on Phys.org
Would appreciate clarifying doubts on the 3 points above!