Quantum mechanics: 1D potential well instananeously expanded to twice its size

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SUMMARY

The discussion centers on a particle in a 1D potential well of length L, which is instantaneously expanded to twice its size. The normalized wavefunctions and energies are derived using the time-independent Schrödinger equation. The probability of measuring the system in the new ground state and first excited state is calculated using the coefficients a_m, where a_1 and a_2 are crucial for the assignment. The final probabilities indicate that the sum of |a_m|^2 for odd m equals 1/2, and |a_2|^2 contributes an additional 1/2, confirming the total probability equals 1.

PREREQUISITES
  • Understanding of the time-independent Schrödinger equation
  • Familiarity with quantum mechanics concepts such as wavefunctions and eigenstates
  • Knowledge of normalization conditions for quantum states
  • Ability to perform integrals involving trigonometric functions
NEXT STEPS
  • Study the derivation of wavefunctions in a 1D infinite potential well
  • Learn about the implications of potential well expansions on quantum states
  • Explore the concept of probability amplitudes in quantum mechanics
  • Investigate the effects of boundary conditions on quantum systems
USEFUL FOR

Students and researchers in quantum mechanics, particularly those focusing on wavefunction behavior in potential wells and the implications of sudden changes in potential. This discussion is beneficial for anyone studying quantum state transitions and probability calculations in quantum systems.

boooster
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Homework Statement



Consider a particle confined in a 1D potential well of length L. Derive the normalized wavefunctions and energies of the eigenstates of the system in terms of the quantum number n, working from the time independent Schördinger equation.
With the particle initially in the ground state (n=1) in the potential, the potential well instantaneously expands to twice it's original size.

Work out the probability, immediately after this change takes place, of measuring the system in (i) its new ground state and (ii) its new first excited state.

Homework Equations


The wavefunction can be written in terms of the eigenstates as follows:

\Psi = \sum_n a_n \phi_m

If we change to a different se of basis states we can write:

\Psi = \sum_m b_m \chi_m

where b_m = \sum_n a_n \int \chi_m^* \phi_n dx

The Attempt at a Solution



\phi_1 = \sqrt{\frac{2}{L}} \sin{\left(\frac{\pi x}{L}\right)}
\chi_m = \sqrt{\frac{1}{L}} \sin{\left(\frac{\pi x m}{2 L}\right)}

I tried to express the probability as \left|a_m\right|^2 where a_m = \int \chi_m^* \phi_1 dx = \int_0^L \frac{\sqrt{2}}{L} \sin{\left(\frac{\pi x}{L}\right)} \sin{\left(\frac{\pi x m}{2L}\right)} dx = \frac{4\sqrt{2}\sin{\frac{m\pi}{2}}}{4\pi -m^2 \pi}

Do you think this approach could be right? a_m^2 equals a nice expression - but unfortunately its infinite sum from m=1 to infinity does not converge ... (it should equal 1).

Thanks for the help!
 
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boooster said:

Homework Statement



Consider a particle confined in a 1D potential well of length L. Derive the normalized wavefunctions and energies of the eigenstates of the system in terms of the quantum number n, working from the time independent Schördinger equation.
With the particle initially in the ground state (n=1) in the potential, the potential well instantaneously expands to twice it's original size.

Work out the probability, immediately after this change takes place, of measuring the system in (i) its new ground state and (ii) its new first excited state.

Homework Equations


The wavefunction can be written in terms of the eigenstates as follows:

\Psi = \sum_n a_n \phi_m

If we change to a different se of basis states we can write:

\Psi = \sum_m b_m \chi_m

where b_m = \sum_n a_n \int \chi_m^* \phi_n dx

The Attempt at a Solution



\phi_1 = \sqrt{\frac{2}{L}} \sin{\left(\frac{\pi x}{L}\right)}
\chi_m = \sqrt{\frac{1}{L}} \sin{\left(\frac{\pi x m}{2 L}\right)}

I tried to express the probability as \left|a_m\right|^2 where a_m = \int \chi_m^* \phi_1 dx = \int_0^L \frac{\sqrt{2}}{L} \sin{\left(\frac{\pi x}{L}\right)} \sin{\left(\frac{\pi x m}{2L}\right)} dx = \frac{4\sqrt{2}\sin{\frac{m\pi}{2}}}{4\pi -m^2 \pi}

Do you think this approach could be right? a_m^2 equals a nice expression - but unfortunately its infinite sum from m=1 to infinity does not converge ... (it should equal 1).

Thanks for the help!

I di dnot check your integral. But it's sure that the sum of a_m^2 you gave from 1 to infinity does converge. But again, I did not check the integration.

Note that you need only a_1 and a_2 for your assignmnent
 
First of all, the problem is ambiguous, because it does not tell you how the walls move. You have assumed that one wall stays put at x=0, and the other moves from x=L to x=2L. If the walls instead moved from x=\pm L/2 to x=\pm L, the answer would be different.

Given your assumption (which is perfectly reasonable), your answer is correct. Note that a_2 has to be obtained by taking a limit, and that the result is a_2=1/\sqrt{2}. All other a_m's with m even are zero. Then, the sum over odd m of |a_m|^2 is 1/2, and adding |a_2|^2 yields at total of one.
 

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