Is My Quantum Well Probability Calculation Correct?

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SUMMARY

The discussion centers on calculating the probability of finding an electron in state n=2 within the central third of an infinite quantum well of width L. The wave function used is Y=Asin(n*pi*x/L), and the user initially calculated the probability as approximately 0.22996. However, further analysis revealed that the correct probability is actually 1/3 minus a small correction factor Δ, which is dependent on n. The final consensus indicates that the user made a calculation error in the integral, leading to the correct answer being approximately 19.6% or expressed as 1/3 - (√3)/(4π).

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Theodore0101
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Homework Statement
An electron is in state n=2 in an infinite quantum well with width L. What is the probability to find the electron if you measure within the well's central third? Can someone cofirm whether or not my solution is correct
Relevant Equations
Y=Asin(n*pi*x/L)
Homework Statement:: An electron is in state n=2 in an infinite quantum well with width L. What is the probability to find the electron if you measure within the well's central third? Can someone cofirm whether or not my solution is correct
Homework Equations:: Y=Asin(n*pi*x/L)

I use the wave funtion Asin(n*pi*x/L) for a wave in a well of the interval 0 to L and square the absolute value of it, getting abs(Asin(n*pi*x/k))^2 = abs(A)^2 *sin^2(n*pi*x/L) (since sin^2(x) is greater or equal to 0) (I use n=2 of course)

I then take the abs(Y)^2 function and integrate it from 0 to L, (using that sin^2(x)`= 1/2(1-cos(2x)) and define the expression as equal to 1 in order to be able to normate it. I get that abs(A)^2*L/2=1 => abs(A)^2 = 2/L

I use 2/L in place of the abs(A)^2 in the integral expression and integrate from L/3 to 2L/3 so that it is the third in the middle. I get that it is equal to 0.229959166. Is this the correct way to solve it? Also, if anyone knows their significant figures, I'm also unsure about how many I am supposed to use in my final answer, since the problem only gives us n=2 which is discrete and that we are calculating for 1/3 of L, and doesn't give any regular values

Thanks
 
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Theodore0101 said:
Homework Statement:: An electron is in state n=2 in an infinite quantum well with width L. What is the probability to find the electron if you measure within the well's central third? Can someone cofirm whether or not my solution is correct
Homework Equations:: Y=Asin(n*pi*x/L)

I use the wave funtion Asin(n*pi*x/L) for a wave in a well of the interval 0 to L and square the absolute value of it, getting abs(Asin(n*pi*x/k))^2 = abs(A)^2 *sin^2(n*pi*x/L) (since sin^2(x) is greater or equal to 0) (I use n=2 of course)

I then take the abs(Y)^2 function and integrate it from 0 to L, (using that sin^2(x)`= 1/2(1-cos(2x)) and define the expression as equal to 1 in order to be able to normate it. I get that abs(A)^2*L/2=1 => abs(A)^2 = 2/L

I use 2/L in place of the abs(A)^2 in the integral expression and integrate from L/3 to 2L/3 so that it is the third in the middle. I get that it is equal to 0.229959166. Is this the correct way to solve it? Also, if anyone knows their significant figures, I'm also unsure about how many I am supposed to use in my final answer, since the problem only gives us n=2 which is discrete and that we are calculating for 1/3 of L, and doesn't give any regular values

Thanks
That answer seems not quite right. Can you check it? Personally, I would give a precise answer, in terms of ##\pi##, and give an approximation to at most 3 decimal places.
 
Last edited:
PeroK said:
That answer seems not quite right. Can you check it? Personally, I would give a precise answer, in terms of ##\pi##, and give an approximation to at most 3 decimal places.

Thanks for your reply. I think I might have done some calculating mistake when I was doing the final step, and that it should instead be 0.33333... or 1/3. Is this the correct answer, or were you referring to something else as being wrong?
 
Theodore0101 said:
Thanks for your reply. I think I might have done some calculating mistake when I was doing the final step, and that it should instead be 0.33333... or 1/3. Is this the correct answer, or were you referring to something else as being wrong?

It's ##\frac 1 3 - \Delta##, where ##\Delta## is some factor that depends on ##n##.

What was the result of your integral?
 
PeroK said:
It's ##\frac 1 3 - \Delta##, where ##\Delta## is some factor that depends on ##n##.

What was the result of your integral?

Using 2/L*int(sin^2(2pi*x/L))dx (from L/3 to 2L/3) I got that it is 1/3 (with 2/L=abs(A)^2 and 2=n). Is it possible for Δ to be 0, or am I still doing something wrong somewhere?
 
Theodore0101 said:
Using 2/L*int(sin^2(2pi*x/L))dx (from L/3 to 2L/3) I got that it is 1/3 (with 2/L=abs(A)^2 and 2=n). Is it possible for Δ to be 0, or am I still doing something wrong somewhere?

##\Delta = 0## for ##n = 3##, but not for ##n =2##.

You can look up the integral of ##\sin^2## to check, but you should get:
$$\int_{L/3}^{2L/3} \frac 2 L \sin^2(\frac{2 \pi x}{L})dx = (\frac 2 L)(\frac{L}{8\pi})\bigg[ \frac{4\pi x}{L} - \sin(\frac{4\pi x}{L}) \bigg ] _{L/3}^{2L/3}$$
 
PeroK said:
##\Delta = 0## for ##n = 3##, but not for ##n =2##.

You can look up the integral of ##\sin^2## to check, but you should get:
$$\int_{L/3}^{2L/3} \frac 2 L \sin^2(\frac{2 \pi x}{L})dx = (\frac 2 L)(\frac{L}{8\pi})\bigg[ \frac{4\pi x}{L} - \sin(\frac{4\pi x}{L}) \bigg ] _{L/3}^{2L/3}$$

Thank you! My mistake seems to have been when doing the integral, and I wrote cos instead of sin in the final expression. But I think I'm getting the correct answer now.
 
Theodore0101 said:
Thank you! My mistake seems to have been when doing the integral, and I wrote cos instead of sin in the final expression. But I think I'm getting the correct answer now.

Which is?
 
PeroK said:
Which is?
About 19.6%
 
  • #10
Theodore0101 said:
About 19.6%

That would be ##\frac 1 3 - \frac{\sqrt{3}}{4\pi}##
 

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