Are you asking about what happens after the two balls collide and instead of motion toward each other there is now motion away from each other?
If so, the two balls are not inertial. SR only states that it's impossible to determine if an inertial object is absolutely at rest or in motion. SR is not claiming that you cannot tell that an accelerated object experiences motion at some time.
So if we follow through on what Nugatory said, we cannot tell if each ball started out at rest and ended up in motion, or started out in motion and ended up at rest, or started out in motion and ended up in a different motion.