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Question about Rydberg equation and molecular orbital

  1. Dec 31, 2008 #1
    Hi, I have a little question about atomic models


    1. Does Rydberg equation only apply to hydrogen

    2. What is the purpose and limitations of molecular obitals
     
    Last edited: Dec 31, 2008
  2. jcsd
  3. Dec 31, 2008 #2

    olgranpappy

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    In principle it should only be applied to hydrogen-like systems--systems with one electron in a Coulomb potential. Anything beyond a one-electron (or effectively one-electron) systems is not exactly solvable, and a Rydberg-type equation involving one-electron energy differences is, in principle, wrong.
    The purpose is to give a simple one-electron type of theory to a more complication many-electron system (a molecule). The limitation are legion, but interestingly molecular orbitals are still useful. A reference that I like regarding orbital theories is a book called "The Physics of the Chemical Bond". The author escapes me at the moment.
     
  4. Dec 31, 2008 #3
    I was wondering if the book is suitable for high school level?



    Thanks for the answer. the explanation is very clear
     
  5. Dec 31, 2008 #4

    olgranpappy

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    hmm... I'm not sure. But, probably it is too advanced for a high school text. Regardless, here is a link to the book on amazon:
    http://www.amazon.com/Electronic-St...=sr_1_1?ie=UTF8&s=books&qid=1230774559&sr=8-1
    maybe you can have a look and see if you think it is too advanced.

    Googling for a high school text on molecular orbitals found me this book which perhaps is useful:
    http://caltechbook.library.caltech.edu/23/1/MOC_1961.pdf
    have a look and let me know. cheers.

    you're welcome.
     
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