Question on bonding and formal charge

In summary, when calculating formal charge, you use the formula (valence electrons in ground state) - lone electrons after bonding - 1/2(bonded electrons). In the example of H2O, the oxygen atom has a formal charge of 0, even though it has 2 more electrons than its ground state. This is because the shared electrons do not fully belong to the oxygen atom. Formal charge is not an actual charge and does not affect the stability of the atom.
  • #1
krackers
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Hello! I was wondering why, when calculating a formal charge, you actually use that formula of (valence electrons in ground state) - lone electrons after bonding - 1/2(bonded electrons)

Lets take H2O.

H - O - H


The O has 6-4-2 = 0 formal charge.
However, the O originally had 6 electrons, and now it has 8, so shouldn't that mean it has a charge of -2 because it has 2 more electrons than before. Also, when that happens, doesn't that mean the number of electrons doesn't match with the number of protons, meaning the atom is now unstable? I would appreciate it if anyone could help to clear this doubt.
 
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  • #2
That is the "Formal" Charge, not an actual charge. Oxygen has 6 electrons, 2 of which them is "shared" with other atoms. They do not fully belongs to O-atom and the other 2 electrons also are shared, so it is not like that 6-proton 8-electron system.
 

1. What is bonding?

Bonding is the process of atoms or molecules joining together to form a chemical compound. This is done through the sharing, donating, or receiving of electrons between atoms.

2. How do you determine the type of bonding in a molecule?

The type of bonding in a molecule can be determined by the difference in electronegativity between the atoms. If the difference is less than 0.4, the bond is considered nonpolar covalent. If the difference is between 0.4 and 1.7, the bond is polar covalent. If the difference is greater than 1.7, the bond is considered ionic.

3. What is formal charge?

Formal charge is a measure of the distribution of electrons in a molecule. It is calculated by subtracting the number of valence electrons allocated to an atom in a Lewis structure from the number of valence electrons in its neutral state.

4. How do you calculate formal charge?

To calculate formal charge, you first need to draw the Lewis structure of the molecule. Then, count the number of valence electrons each atom has and compare it to the number of valence electrons in its neutral state. The formal charge is calculated by subtracting the number of valence electrons from the number of valence electrons in its neutral state.

5. What is the significance of formal charge in a molecule?

Formal charge helps in determining the most stable Lewis structure for a molecule. It also helps in understanding the distribution of electrons in a molecule, which can affect its reactivity and properties. Additionally, formal charge can also be used to determine the charges on individual atoms in a molecule, which is important in understanding its overall charge and polarity.

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