Question on bonding and formal charge

  • Thread starter Thread starter krackers
  • Start date Start date
  • Tags Tags
    Bonding Charge
Click For Summary
SUMMARY

The discussion focuses on the calculation of formal charge, specifically using the formula: (valence electrons in ground state) - lone electrons after bonding - 1/2(bonded electrons). In the example of water (H2O), the oxygen atom has a formal charge of 0, calculated as 6 - 4 - 2 = 0. The confusion arises from the perception that oxygen, having 8 electrons after bonding, should have a charge of -2; however, this does not account for the shared nature of the electrons in covalent bonds. The formal charge concept clarifies that the atom's stability is maintained despite the apparent discrepancy in electron count.

PREREQUISITES
  • Understanding of valence electrons and their role in bonding
  • Familiarity with the concept of formal charge in chemistry
  • Knowledge of covalent bonding and electron sharing
  • Basic grasp of atomic structure, including protons and electrons
NEXT STEPS
  • Study the principles of covalent bonding and electron sharing in detail
  • Learn about the significance of formal charge in molecular stability
  • Explore examples of formal charge calculations for various molecules
  • Investigate the relationship between formal charge and resonance structures
USEFUL FOR

Chemistry students, educators, and anyone interested in understanding molecular structure and stability through formal charge calculations.

krackers
Messages
72
Reaction score
0
Hello! I was wondering why, when calculating a formal charge, you actually use that formula of (valence electrons in ground state) - lone electrons after bonding - 1/2(bonded electrons)

Lets take H2O.

H - O - H


The O has 6-4-2 = 0 formal charge.
However, the O originally had 6 electrons, and now it has 8, so shouldn't that mean it has a charge of -2 because it has 2 more electrons than before. Also, when that happens, doesn't that mean the number of electrons doesn't match with the number of protons, meaning the atom is now unstable? I would appreciate it if anyone could help to clear this doubt.
 
Chemistry news on Phys.org
That is the "Formal" Charge, not an actual charge. Oxygen has 6 electrons, 2 of which them is "shared" with other atoms. They do not fully belongs to O-atom and the other 2 electrons also are shared, so it is not like that 6-proton 8-electron system.
 

Similar threads

Replies
3
Views
2K
Replies
5
Views
3K
Replies
32
Views
5K
  • · Replies 3 ·
Replies
3
Views
4K
  • · Replies 8 ·
Replies
8
Views
2K
Replies
9
Views
4K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 6 ·
Replies
6
Views
1K
  • · Replies 9 ·
Replies
9
Views
3K