Questions about super critical boilers

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SUMMARY

This discussion focuses on supercritical boiler systems in pulverized coal power plants, specifically addressing the nature of supercritical fluids and their operational differences compared to sub-critical systems. A supercritical fluid exists above the critical point, where distinct liquid and gas phases do not exist. In supercritical boiler operation, the fluid is maintained at pressures above 22 MPa, eliminating the need for a steam drum and allowing for more efficient energy transfer without phase changes. The discussion also highlights the necessity for higher purity water in supercritical systems due to the increased risk of impurities affecting performance.

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  • Understanding of thermodynamics, specifically critical points and phase transitions.
  • Knowledge of boiler operation principles, including supercritical and sub-critical systems.
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  • Basic concepts of water chemistry and its impact on boiler efficiency.
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ehilge
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I have a couple questions on supercritical boiler systems with reference to pulverized coal power plants.

My first question concerns what exactly a supercritical fluid is. I realize that the phrase 'supercritical' means above the critical point where there is no clear distinction between liquid and gas, or the mixture is homogenous. I think part of my problem is visualizing what exactly such a homogenous fluid is, or how it behaves if that makes any sense. How does something actually transition from sub-critical to supercritical? i.e. to go from liquid to gas, you boil. Is there a process something goes through to become a critical fluid or does it just sort of happen?

Moving on, how does supercritical boiler operation compare to a sub-critical plant? My understanding is that (ideally) the fluid is pressurized above about 22MPa by the feedwater pumps, and remains there until it goes through the turbine. Of course, between those two points we go through the boiler. But in this case, we aren't boiling anything, right? Because there's no phase change to go through. We are just adding heat energy to the supercritical boiler. One of my sticking points is that I have been told supercritical plants use a seperator instead of a steam drum. Of course, a steam drum isn't needed because there's no steam to separate from liquid, there's just this supercritical fluid. So what is the purpose of a seperator if there is nothing to separate?

Furthermore, is the reason why supercritical plants are more efficient than sub-critical due to the fact that there is no phase change to suck up energy?

Sorry for the long post, but I have some questions here I'd like to clear up. Thanks for your help!
 
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Another question I thought of. I've read that the water in a supercritical system needs to be more pure than that of a subcritical system, why is that?
 

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