Quick Question about theory in solving Ksp?

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The discussion centers on calculating the equilibrium concentration of Pb²⁺ ions after mixing solutions of Pb(C₂H₃O₂) and K₂CrO₄, leading to the precipitation of PbCrO₄. The user questions whether it's necessary to treat the reaction as a limiting reagent problem and complete the reaction before using an ICE chart for solubility calculations. They found that both methods yield the same numerical result but seek clarification on the legitimacy of each approach. Responses suggest that while using the ICE chart is standard practice, directly calculating the equilibrium can also be valid if it leads to the correct answer. Ultimately, both methods are acceptable, depending on the context and requirements of the problem.
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Homework Statement



[/B]
Lead chromate, PbCrO4, is a yellow pigment used in paints. Suppose 0.50 L of a 1.0 x 10-5 M Pb(C2H3O2) and 0.50 L of a 1.0 x 10-3 M K2CrO4 solution are mixed. Calculate the equilibrium concentration of Pb+2 ion remaining in the solution after PbCrO4 precipitates. What is the percentage of Pb+2 remaining in solution after the precipitation has occurred. (The Ksp for PbCrO4 is 1.8 x 10-14)I have a little question regarding theory about how a website solved this problem.

Homework Equations


The solution is here on page 21 of the document.
http://faculty.icc.edu/bcook/chem132NT/acid_base_eq.pdf

The Attempt at a Solution



My question is this: is it really necessary to assume initially that this is a limiting reagent problem and have the reaction of Pb2+ and CrO42- go to completion to form the salt and then do the ICE chart calculation for the solubility, or is it OK if I just go and do the ice chart straight away?

I tried both methods, and both gave the same numerical answer, but which approach is more "legit"?

Thanks in advance.
 
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"ICE?" If you have to use it to satisfy "OC" types, do so. Otherwise, plug it in and grind it out.
 

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