Quick question on iodination of acetone.

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Discussion Overview

The discussion revolves around the iodination of acetone in a kinetics lab experiment, focusing on the concentration of iodine compared to other reactants and its impact on the reaction rate. Participants explore the implications of iodine's low concentration in the context of reaction orders and rate constants.

Discussion Character

  • Technical explanation, Experimental/applied, Conceptual clarification

Main Points Raised

  • One participant notes that the concentration of iodine is much lower than that of acetone and HCl, questioning the rationale behind this choice.
  • Another participant suggests that the slow rate of reaction is due to the low concentrations of acetone and H+, and that iodine being zero order means its low concentration does not affect the rate.
  • A different participant mentions that low concentrations of iodine may be used for economic reasons or to minimize health hazards due to its toxicity.
  • It is noted that monitoring the loss of yellow iodine color helps track the reaction, and concentrated iodine solutions may not yield linear results according to Beer's law.
  • One participant argues that increasing iodine concentration could extend the reaction duration, potentially leading to more accurate measurements.

Areas of Agreement / Disagreement

Participants express varying views on the implications of iodine's concentration, with some agreeing on its zero-order nature while others discuss practical considerations without reaching a consensus on the optimal concentration strategy.

Contextual Notes

Participants do not fully resolve the reasons for the chosen iodine concentration, and assumptions regarding the effects of concentration on reaction rates remain implicit.

Who May Find This Useful

This discussion may be useful for students and researchers interested in reaction kinetics, particularly in the context of iodination reactions and the effects of reactant concentrations on reaction rates.

Alex48674
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In class today we did a lab with acetone (4M), iodine (.0050M), and HCl (1.0M). The lab was one kinetics and on determining the rate constant, rates, and orders. Which I've done fine, but I'm stuck on this question: Why is the concentration of I2 so much less then the other reactants?

Any help would be appreciated, and it's due tomorow =]

Btw

Rate=2.1 (Ms)^(-1) x 10^(-5) x (Acet) x (H+)

Second order reaction.

First order with respect to Acet and H+, zero order with respect to I2

Just to prove I've done the work =]
 
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the rate of reaction is already slow because of the acetone and H+ reacting. if you use low concentrations of them, the reaction would be even slower.

and since iodine is zero order, using a very low concentration does not affect the rate. probably you have been given low concentration because of economic reasons or maybe to reduce health hazards when pipetting iodine, because it is toxic.
 
Ahhh thanks, that makes sense.
 
You followed the rate of reaction by monitoring the loss of yellow (iodine) color in solution. Concentrated solutions of iodine would not likely give you linearity with respect to concentration (Beer's law).
 
i guess this makes more sense!
 
Iodine is the main determinant in the reaction. So, the reaction will continue until it's gone. Therefore, increasing the concentration of Iodine would cause the reaction to go on much longer and usually a reaction that only takes a few minutes gives you much easier and more accurate numbers to deal with.
 

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