R/S Configuration and Identical Compounds

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The discussion revolves around a student's confusion regarding the R/S configuration of two compounds that are claimed to be identical. The student consistently arrives at R for one compound and S for the other, despite the key indicating they should have the same configuration. Misunderstandings about the priority assignments of substituents, particularly between CH2CH2OH and CH2CH3, are highlighted as a potential source of error. The correct method involves positioning the lowest priority group behind the central carbon and then determining the configuration based on the arrangement of the remaining groups. Clarification on these priority assignments and the proper rotation technique is essential for resolving the student's confusion.
cathy
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Homework Statement



Hello, so I think I've been looking at this problem way too long, and I'm going no where with it. It is in my attached picture, because it is easier to draw than write out on here.
The key says these two are identical compounds, meaning they should have the same configuration.
But, I keep on getting R for the first and S for the second.
I got R for the first by switching the configuration since the 4th one should be going away, but it is rather coming towards me. I got S by following the priorities. Would someone be able to tell me where I am going wrong, please? I am very confused.
 

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Am I drawing all the priorities correctly?
I keep looking at my solution manual and I'm getting all opposite answers for all the questions :(. Is there something crucial I'm missing here?
 
Last edited:
The priorities of CH2CH2OH and CH2CH3 should be 3 and 4, respectively as O has higher priority than H. You seem to have assigned them the other way round.
To assign R or S to the structures, you have to rotate the molecule so that substituent 4 lies behind the central C and then determine the direction from 1 over 2 to 3.
 

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