Radius of the electron orbit in a Hydrogen atom

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Homework Help Overview

The discussion revolves around calculating the radius of the electron orbit in a hydrogen atom, specifically focusing on the quantum number and energy levels associated with the electron's state.

Discussion Character

  • Exploratory, Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants explore deriving expressions for energy in relation to quantum number n and the radius of the electron orbit. Questions arise regarding the appropriate values for n and how to incorporate given energy values into their calculations.

Discussion Status

Participants have shared various expressions and attempted to relate energy levels to the quantum number n. Some have noted confusion about the total energy and the implications of negative energy values. There is an ongoing exploration of how to correctly interpret the energy levels and their relationship to the radius.

Contextual Notes

Participants are working within the constraints of provided energy values and the requirement to derive relationships without complete solutions. There is mention of potential discrepancies in the answer options related to the calculated radius.

Bolter
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Homework Statement
See question below
Relevant Equations
F = mv^2/r
I am really stuck on what to do here in this question

Screenshot 2020-03-28 at 15.26.02.png


I have arrived at forming an equation to work out the radius of electron orbit from doing the following

IMG_4368.jpg


However I do not know what to do next as I don't know what the value of n (quantum number) must be? :oldconfused:

Any help would be really great! Thanks
 
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Derive an expression for the energy since you're provided the energy of the electron.
 
vela said:
Derive an expression for the energy since you're provided the energy of the electron.

I have tried doing that and get this

IMG_4370.JPG


What would my total energy E be though? That is my confusion
 
Try writing the energy in terms of ##n## instead of ##r##. Then you can find the allowed energies by plugging in different values for ##n##.
 
vela said:
Try writing the energy in terms of ##n## instead of ##r##. Then you can find the allowed energies by plugging in different values for ##n##.

Is this the expression that I need which I circled in my working for the total energy in terms of ##n##?

IMG_4372.jpg


How would I do this as I have a ##v## in my expression which I do not know? And it is ##r## that we are trying to find?
 
You already found expressions for the kinetic and potential energy in terms of ##r##, and you have ##r## in terms of ##n##. Just put those together.
 
vela said:
You already found expressions for the kinetic and potential energy in terms of ##r##, and you have ##r## in terms of ##n##. Just put those together.

Thanks I have tried putting these together and have ended up with this expression

B43CC796-F3AB-4DEB-B5A9-9712A93DEFAF.jpeg

CB60A786-F1EA-409E-AFA9-658C11C9D5D9.jpeg


Now how do I make use of the 0.85eV and 12.75eV values given in the question to find radius?
 
Shouldn't the energy in the excited state be -0.85eV? At zero it would become unbound.
 
haruspex said:
Shouldn't the energy in the excited state be -0.85eV? At zero it would become unbound.

I was thinking that too as usually energy level values are negative

Is it wrong to think that the total energy E would be 0.85eV + 12.75eV = 13.6 eV?
 
  • #10
I know that I shouldn't be looking at this but here is the energy level diagram for a hydrogen atom

Screenshot 2020-03-28 at 22.43.03.png


Therefore I know that my energy En = –0.85eV is in the 4th energy level hence n = 4

Problem is that when I sub different integer values of ##n## in the equation that relates energy ##E## in terms of ##n## I keep getting zero on my calculator?
 
  • #11
Bolter said:
I was thinking that too as usually energy level values are negative

Is it wrong to think that the total energy E would be 0.85eV + 12.75eV = 13.6 eV?
On reflection, I don't think the 0.85 matters. The key should be the 12.75eV difference between E1 and En.
You have expressions for both of those from post #7.
 
  • #12
haruspex said:
On reflection, I don't think the 0.85 matters. The key should be the 12.75eV difference between E1 and En.
You have expressions for both of those from post #7.

Thank you, I used what I had in post #7 where I knew that energy in En = –0.85eV

Then from that I done:

IMG_4375.jpg


So radius is 8.46 angstroms to 2 dp
 
  • #13
Notice this is 42=16 times the Bohr radius (=.529Angstrom) as it should be.
 
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  • #14
hutchphd said:
Notice this is 42=16 times the Bohr radius (=.529Angstrom) as it should be.

Right, so I should divide my 8.462... angstrom by 16 to get 0.529 angstrom

Also I should've showed the full question in the original post by showing the possible answers to choose from

Here it is

Screenshot 2020-03-29 at 13.07.04.png

As you can see there isn't any 0.529 angstrom option here? Does this question have an error then? I thought option b would've been the correct answer.
 
  • #15
You misunderstand. The answer you provide is correct. The Bohr radius is the size of the n=1 (ground) state. I was pointing out there was an easier route to your answer but all correct routes will provide the correct number!
 
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  • #16
hutchphd said:
You misunderstand. The answer you provide is correct. The Bohr radius is the size of the n=1 (ground) state. I was pointing out there was an easier route to your answer but all correct routes will provide the correct number!

Oh I see, I understand what you had meant now, my bad
 
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