Reducing the conductivity of silanol group

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Discussion Overview

The discussion centers on methods to reduce the conductivity of silanol groups in glass channels during electromosis, with a focus on surface treatment techniques. Participants explore various approaches and their implications for maintaining the functionality of the glass in aqueous solutions.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant mentions using OTS treatment but notes it makes the channels too hydrophobic for aqueous solutions.
  • Another participant suggests heating the glass to condense silanol groups, proposing a chemical reaction that removes water.
  • A different participant questions whether heating might damage the glass, expressing concern about the stability of the material at high temperatures.
  • One participant highlights the importance of silanol groups in creating a double layer by exchanging protons, raising concerns about the effects of condensing these groups.
  • Another participant points out that the optimal heating parameters (temperature and duration) are specific to the problem and suggests that some silanol groups may need to be retained to maintain functionality.
  • It is noted that OTS treatment would also remove silanol groups, which could eliminate the double layer effect.

Areas of Agreement / Disagreement

Participants express differing views on the implications of heating glass and the effects of silanol group condensation, indicating that multiple competing perspectives remain unresolved.

Contextual Notes

There are uncertainties regarding the specific heating parameters required and the balance between reducing conductivity and maintaining the necessary proton exchange functionality.

frenchero
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Hi,

I am performiong electromosis into glass channels and I would like to reduce the silanol group conductivity. I am not an expert in surface treatment and I only know treatment with OTS but it makes the cannel become too hydrophobiac to use aquaeous solutions and that's hat I am using.
Any body has an idea?

Thank you.
 
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Try heating the glass to condense the silanol groups by removing water.

-Si-OH + HO-Si- ---> Si-O-Si + H2O
 
but would not heating cause extra damages to the glass before the silanol groups condense? I mean in this form glass is pretty stable and you will have to heat at high temperature won't you?
 
another really important that I forgot to mention is that the silanol groups create a double layer in my system by exchanging protons so I need to keep protons which I do not if I condense silanol groups.
 
How much to heat and for how long appears to be a unique set of parameters for your problem. You will need to keep some but perhaps not all?

BTW treatment with OTS will remove the silanol groups as well... bye, bye double layer!
 

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