Riemann vs. Lebesgue integral in QM

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Discussion Overview

The discussion revolves around the comparison between Riemann and Lebesgue integrals in the context of quantum mechanics (QM), specifically regarding the properties of wavefunctions in Hilbert space. Participants explore the implications of using different types of integrals for defining the space of square-integrable functions and their relevance to quantum mechanics.

Discussion Character

  • Technical explanation
  • Debate/contested

Main Points Raised

  • Some participants assert that Hilbert space in QM typically involves Lebesgue-integrable functions due to completeness requirements, which are not satisfied by Riemann integration.
  • There is a request for examples of wavefunctions whose modulus squared is Lebesgue integrable but not Riemann integrable, highlighting a potential gap in understanding.
  • Some participants note that wavefunctions in practice are usually real analytic, but general results in quantum mechanics require limits in the topology defined by the 2-norm.
  • There is a discussion about the definition of the 2-norm and its implications for wavefunctions, with some clarification provided on the notation used.
  • One participant suggests that the norm might need to account for time dependence, while another clarifies that the relevant Hilbert space is L²(ℝ³) and that time-dependent wavefunctions can be viewed as curves in this space.
  • A question is raised about the appropriateness of using ℝ⁴ instead of ℝ³ for the configuration space, with a response indicating that the dynamics described by the Schrödinger equation pertain specifically to ℝ³.
  • In the context of the infinite square well problem, a participant questions whether Riemann integrals are sufficient or if Lebesgue integrals are still necessary, with a response indicating that Lebesgue integrals are required to establish a Hilbert space.

Areas of Agreement / Disagreement

Participants express differing views on the necessity of Lebesgue integrals versus Riemann integrals in defining Hilbert space for quantum mechanics. While some assert the need for Lebesgue integrals, others question the sufficiency of Riemann integrals in specific cases, indicating that the discussion remains unresolved.

Contextual Notes

Participants mention the completeness requirement of Hilbert space and the potential divergence of integrals over ℝ⁴, suggesting limitations in the application of Riemann integrals in certain contexts.

AxiomOfChoice
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When we talk about "Hilbert space" in (undergraduate) QM, we are typically talking about the space of square-integrable functions so that we can make sense out of
[tex] \int_{-\infty}^{\infty} |\psi(\vec r,t)|^2 d^3x.[/tex]
But are we talking about Riemann-integrable functions or Lebesgue-integrable functions? Can someone give me an example of a wavefunction that arises in practice whose modulus squared is Lebesgue integrable but NOT Riemann integrable? Don't wavefunctions (and hence their modulus squares) have to satisfy certain continuity conditions, implying that the Riemann integral is sufficient?

I realize that writing the limits of integration above from [itex]-\infty[/itex] to [itex]\infty[/itex] might, to some, imply that we're talking about a Lebesgue integral, since Riemann integrals are by definition defined only on closed, bounded intervals. But I suppose it's possible that we're just talking about an improper Riemann integral instead.
 
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They are talking about Lebesgue-integrable functions. No matter what functions show up in practice you need the Hilbert space. There is a completeness requirement in the definition of Hilbert space, which is used in many theorems and cannot be avoided, that you don't have if only Riemann integration is considered.
 
AxiomOfChoice said:
Can someone give me an example of a wavefunction that arises in practice whose modulus squared is Lebesgue integrable but NOT Riemann integrable?
Wave functions that arise in practice are typically real analytic. But if one wants to prove general results about quantum mechanics, one needs to be able to take limits in the topology defined by the 2-norm. But the space of functions whose modulus squared is Riemann integrable is not a Hilbert space.
 
A. Neumaier said:
Wave functions that arise in practice are typically real analytic. But if one wants to prove general results about quantum mechanics, one needs to be able to take limits in the topology defined by the 2-norm. But the space of functions whose modulus squared is Riemann integrable is not a Hilbert space.

By "2-norm", do you mean the norm given by

[tex] \| \psi \| = \sqrt{\int_{-\infty}^\infty \psi(\vec x,t) \psi^*(\vec x,t) d^3 x}[/tex]
 
AxiomOfChoice said:
By "2-norm", do you mean the norm given by

[tex] \| \psi \| = \sqrt{\int_{-\infty}^\infty \psi(\vec x,t) \psi^*(\vec x,t) d^3 x}[/tex]
Yes.
 
AoC, you should either drop the time dependence on the right-hand side, or introduce a t on the left as well. (The first option is better, if all you want to do is to define a norm on [itex]L^2(\mathbb R^3)[/itex]).
 
perhaps then this norm is over [tex]R^4[/tex] since our wave functions are time dependent
 
homology said:
perhaps then this norm is over [tex]R^4[/tex] since our wave functions are time dependent
No, the relevant Hilbert space is [itex]L^2(\mathbb R^3)[/itex]. You should think of the time-dependent wavefunctions as curves in that space. More precisely, if we define [itex]\psi_t[/itex] by [itex]\psi_t(\vec x)=\psi(\vec x,t)[/itex] for all [itex]\vec x[/itex], then [itex]\psi_t[/itex] is a member of [itex]L^2(\mathbb R^3)[/itex] and [itex]t\mapsto\psi_t[/itex] is a curve in [itex]L^2(\mathbb R^3)[/itex].
 
Fredrick,

why is this the case? that is, what would be the mistake with using R^4?

though it seems that what you're saying, resembles the case in mechanics where you gave an inner product at each point on the configuration manifold and the parameter t moves you along this surface through different tangent spaces, us that what you're after?
 
  • #10
homology said:
why is this the case? that is, what would be the mistake with using R^4?

though it seems that what you're saying, resembles the case in mechanics where you gave an inner product at each point on the configuration manifold and the parameter t moves you along this surface through different tangent spaces, us that what you're after?
The configuration space of a single particle is R^3, not R^4, and the Schroedinger equation describes the dynamics how a wave function in L^2(R^3) changes with time.

If you were to integrate over R^4, all integrals would diverge.
 
  • #11
oh of course, doh...the inner product is only over space...ack...shouldn't respond to these things in the morning
 
  • #12
If we considered the infinite square well problem, where the domain is compact, is the Riemann integral sufficient, or do we still need the Lebesgue integral?
 
Last edited:
  • #13
You still need the Lebesgue integral to get a Hilbert space. I think you can e.g. find a sequence of Riemann integrable functions (all with the same compact domain) that converges pointwise to a function that isn't Riemann integrable.
 

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