Rotating Ideal Gas: Homework Eqns & Boltzmann Dist

Click For Summary
SUMMARY

The discussion focuses on the analysis of an ideal gas in a rotating cylindrical container, specifically addressing the energy states of single particles and the Boltzmann distribution. The energy equation is defined as E = p²/(2m) + V(r), where V(r) represents the centrifugal potential energy. There is confusion regarding the distinction between the partition function Z and the Boltzmann distribution, with clarification needed on how to separate the distribution into translational and interaction components. The discussion also highlights the challenge of performing a 3D momentum integral, which is essential for deriving the Boltzmann distribution in this context.

PREREQUISITES
  • Understanding of ideal gas laws and properties
  • Familiarity with Boltzmann distribution and partition function concepts
  • Knowledge of classical mechanics, particularly rotational dynamics
  • Experience with multivariable calculus and integrals in physics
NEXT STEPS
  • Study the derivation of the Boltzmann distribution in rotating systems
  • Learn about partition functions in statistical mechanics
  • Explore techniques for evaluating 3D integrals in physics
  • Investigate the implications of centrifugal potential energy on gas behavior
USEFUL FOR

Students and professionals in physics, particularly those studying thermodynamics and statistical mechanics, as well as anyone working with ideal gases in rotating systems.

Brewer
Messages
203
Reaction score
0

Homework Statement


An ideal gas of N molecules of mass m is contained in a cylinder of length
L and radius R. The cylindrical container is rotating about its axis at an
angular velocity \omega, and is at equilibrium with temperature T.

Write down the energy for single particle states, and the Boltzmann distribution for the gas in the rotating cylinder given it experiences a centrifugal potential energy V(r)

Homework Equations


the energy is just E = \frac{p^2}{2m} + V(r)

I'm not entirely sure about the Boltzmann distribution. In my notes it states that Z_1 = \int \frac{d^3 rd^3p}{h^3} e^{-\beta E}

However here I get confused. I was pretty sure that Z is the partition function of the gas (which it has been so far), but a few lines further in the notes it calls this the Boltzmann distribution. As far as I was aware these aren't interchangeable names, and are completely separate things within the frame work of statistics.

The question goes onto to ask me to split the Boltzmann distribution into a translational and a interation part, which I know can be done with the above equation (another reason I'm hedging my bets on using this equation for the Boltzmann distribution). Whilst this is fine in theory I'm a little concerned about doing this in practice. I know one of the parts is an integral over 3d space with the kinetic part of the energy and the other bit is the integral over what seems to be 3d momentum with the potential part (I think I may have got the combinations back to front, but I'll check that - that's not the bit I'm confused with). My problem with this is the 3d momentum integral. I have never seen how to do this (or even seen anything like it before!) so could you suggest how I'd go about solving this bit. Is it anything like the the 3d integral over space in which you have various factors to add to it, or does it work completely differently?
 
Last edited:
Physics news on Phys.org
Boltzmann distribution--or is it called "gibbs distribution--is the integrand (suitably normalized)
<br /> e^{-\beta E}<br />
 
to do the momentum integral is the easy part. use
<br /> \int_{-\infty}^{\infty}dx e^{-\alpha x^2}=\sqrt{\frac{\pi}{\alpha}}<br />
 

Similar threads

Replies
1
Views
2K
  • · Replies 4 ·
Replies
4
Views
3K
  • · Replies 0 ·
Replies
0
Views
1K
  • · Replies 3 ·
Replies
3
Views
1K
  • · Replies 4 ·
Replies
4
Views
3K
  • · Replies 5 ·
Replies
5
Views
3K
  • · Replies 4 ·
Replies
4
Views
5K
Replies
5
Views
2K
  • · Replies 27 ·
Replies
27
Views
5K
  • · Replies 1 ·
Replies
1
Views
2K