Salt water and potential difference

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Discussion Overview

The discussion revolves around the behavior of salt water in the presence of two electrodes at different potentials (+500V and +250V) and the implications for ion movement and potential distribution within the salt water. Participants explore theoretical models, potential gradients, and the effects of conductivity on the system.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • One participant suggests that as negative ions leave the salt water to reach the electrodes, the potential of the salt water will rise until it exceeds +250V, leading to a shift in ion movement.
  • Another participant questions the meaning of "potential of salt water" and proposes different models for understanding the situation, including comparing it to a resistor or a conductor.
  • Several participants assert that the potential of the salt water will stabilize at 375V, creating equal potential differences between the electrodes.
  • Concerns are raised about the conductivity of the salt water affecting the voltage distribution, with implications for short-circuiting the voltage source if the solution is highly conductive.
  • One participant notes that the voltage within the salt water will vary according to Ohm's law, indicating a gradient rather than a uniform potential.
  • Another participant emphasizes that maintaining the salt water at 0V is not feasible given the potentials of the electrodes.
  • Discussion includes the relevance of electrical capacitance and the work done in the system, with references to the behavior of electrolytic cells.
  • A participant mentions external resources, suggesting further exploration of related concepts.

Areas of Agreement / Disagreement

Participants express differing views on the behavior of the salt water's potential and the implications of conductivity, indicating that multiple competing models and interpretations remain unresolved.

Contextual Notes

Participants highlight limitations in their assumptions regarding the behavior of the salt water and the potential gradients, as well as the dependence on the conductivity of the solution.

Tryhard314
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Imagine a container of salt water at 0V (Relative to ground),Now you've put in it 2 electrodes,one at +500V (Electrode A), The other at +250V(Electrode b), Normally positive ions should go to the negative electrode , and Negative ions should go to the positive electrode , But in our example the salt water is at 0V So you would have to do positive work to go to those electrodes. But because a negative charge do a negative work to reach a higher potential, they will be attracted to both electrodes, But there would be a higher attraction for the +500V than the 250+,

My Idea is this: With more and more negative ions leaving the salt water to get dissolved in the electrodes, Salt water potential will rise until it's >250V because if salt water potential raises more than +250V positive ions will start being forced to go to the 250V electrode because it's at a lower potential, and no more negative ions will go to the +250V because they would need to do positive work to go from salt water to that electrode.

Further more I think salt water's potential will reach exactly 375V, because at this value the potential difference between Electrode A (500V) and Salt water(375V) = 125V, and the potential difference between Salt water(375V) and electrode B (250V) = 125V
So the number of positive ions that go the Electrode B is equal to the number of negative ions that go to the electrode A
 
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What does "potential of salt water" mean?

Can we model this situation as a resistor whose two ends are connected to two potentials, or as a conductor whose two ends are connected to two potentials?

In the first case potential somewhere between the electrodes is between the potentials of the electrodes.

In the second case there is a huge explosion, I mean something must break in the second case.
 
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Thread is in Moderation temporarily for review...

Thread re-opened for discussion. Thanks for your patience.
 
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Tryhard314 said:
Further more I think salt water's potential will reach exactly 375V, because at this value the potential difference between Electrode A (500V) and Salt water(375V) = 125V, and the potential difference between Salt water(375V) and electrode B (250V) = 125V
So the number of positive ions that go the Electrode B is equal to the number of negative ions that go to the electrode A
It depends on how conductive the salt water solution is. If it's very conductive, it will short out your voltage source. If it's not very conductive, you will end up with electric field lines defining the potentials and the voltages inside the "grounded" equipotential cylinder and between the electrodes. Think of extending this simulation plot to the case where there is a surrounding equipotential cylinder...

https://encrypted-tbn0.gstatic.com/...-aUKtQMbl-CC5sUK4mmSTfmgRuWwl_nuwBh7DKp5LLw&s
1573693828522.png
 
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Tryhard314 said:
I think salt water's potential will reach exactly 375V, because at this value the potential difference between Electrode A (500V) and Salt water(375V) = 125V, and the potential difference between Salt water(375V) and electrode B (250V) = 125V
There is a current through the salt water so by ohms law the voltage will vary within the water itself. Near electrode B it will be near 250 V and near electrode A it will be near 500 V.
 
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Tryhard314 said:
But in our example the salt water is at 0V
You can't keep it there with ony two electrodes at +250 and +500 V
 
Dale said:
There is a current through the salt water so by ohms law the voltage will vary within the water itself. Near electrode B it will be near 250 V and near electrode A it will be near 500 V.
After writing for 1 hour,I realized that in my first post i worked for the average value of potential inside the salt water,and you just described how the potential gradient is inside the salt water because there can't be a direct drop from +500 to 375V ,I leave you this paint image of my circuit if someone want to use it someday And Thanks !
salt water.png
 
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Tryhard314 said:
So you would have to do positive work to go to those electrodes. But because a negative charge do a negative work to reach a higher potential, they will be attracted to both electrodes, But there would be a higher attraction for the +500V than the 250+,
The container will have Electrical Capacitance to Earth of only a few hundred picoFarads and the amount of charge that needs to flow in order to bring one electrode to 250V would be perhaps a microCoulomb. The Work Done will be minuscule (CV2/2)After that, the only relevant Potential would be the PD between the two electrodes and you've got a normal electrolytic cell, through which will be flowing many Coulombs per second.
The Potential relative to Earth in many situations is very often irrelevant. Exceptions: Appreciable initial current will flow to the helicopter during hot wire maintenance of very high voltage lines and, of course, the current that can flow from your hand to a MOS circuit can be relevant - requiring an Earth strap for circuit construction. Mains voltage circuits have very few 'static charge' effects.
 
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do a google search on "Liquid motor starters"
 
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