Schrodinger's Equation validity for relativistic particles

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Schrödinger's equation is not valid for relativistic particles primarily because it is not Lorentz-invariant, which contradicts the principles of special relativity. The discussion highlights that while the general form of the Schrödinger equation is assumed valid for all physical systems, its applicability is limited by the Hamiltonian's form. The Klein-Gordon equation, being second-order in time, presents challenges in relating it to the Schrödinger framework, particularly regarding its Hamiltonian. The conversation also touches on the complexities of quantizing fields in a relativistic context, emphasizing the differences between non-relativistic and relativistic quantum mechanics. Overall, the limitations of Schrödinger's equation in describing relativistic particles are underscored by its failure to maintain consistency with fundamental physical principles.
  • #31
This is a question involving the semantic on the statement

"The SE is not Lorentz invariant"

I'm trying to prove that the SE isn't Lorentz Invariant.

I think I've showed it. I'd just like some input on my argument.

Under the change of coordinates:

x^\mu \mapsto x'^{\mu}=\Lambda^\mu_{\phantom{1}\nu} x^\nu

Covariantly;

\partial_\mu \mapsto \partial_{'\mu}=\Lambda_\mu^{\phantom{1}\nu} \partial_{'\nu}

And the wavefunction;

\psi(x)\mapsto \psi'(x')=S(\Lambda)\psi(x)

where S(\Lambda) is just some linear function.

The SE:

\{\iota \hbar\partial_t+\frac{\hbar^2}{2\mu} \partial_\nu \partial_\nu \}\psi(x)=0

where \nu=1,2,3.

Trasforming \psi(x) \mapsto \psi'(x') and multiplying by S^{-1}(\Lambda), and transforming the partial derivatives, we get

\{\iota \hbar\Lambda_0^{\phantom{1}\nu} \partial_{'\nu}+\frac{\hbar^2}{2\mu} \sum^{3}_{i=1}\Lambda_i^{\phantom{1}\alpha}\Lambda_i^{\phantom{1}\beta}\partial_{'\alpha} \partial_{'\beta} \} \psi'(x')=0

On comparing this to the "primed" SE. We find that the conditions \Lambda must satisfy are

\Lambda_0^{\phantom{1}\nu} \partial_{'\nu}=\partial_{'0}

and

\sum^{3}_{i=1}\Lambda_i^{\phantom{1}\alpha}\Lambda_i^{\phantom{1}\beta}\partial_{'\alpha} \partial_{'\beta} = \partial_{'\nu} \partial_{'\nu}.

Now, my question is, for me to prove that the SE isn't Lorentz invariant, do I need to show

a) that no such \Lambda \in \mbox{O(1,3)} can exist

or

b) is it sufficient to pick some \Lambda' \in \mbox{O(1,3)} and show that it doesn't satisfy the above condition ("counterexample").

If b) is indeed sufficient, could someone explain why, as it would seem that the SE is Lorentz invariant for certain matrices \in \mbox{O(1,3)}, and what does this mean to the statement:

"The SE equation is not Lorentz invariant"

Thank you
 
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  • #32
Looking back on this question, I suppose I could cut out all the texing and just simply ask:

If I show that \exists a \Lambda \in O(1,3) which the Schrodinger Equation does not transform covariantly under, is this enough to say that the SE isn't Lorentz Covariant.

Because trivially, if I take the identity, it's going to work. And presumably others work. So certain transformations will work, but not all.

So my question is: is it sufficient to show a counterexample in O(1,3) (which I have) to make the "SE not Lorentz Covariant" statement.

Thank you
 

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