Show these wavelengths are consistent with Rydberg formula

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SUMMARY

The discussion focuses on demonstrating that the wavelengths 18.226 nm, 13.501 nm, and 12.054 nm are consistent with the Balmer series for hydrogen-like atoms using the rearranged Rydberg formula. The formula used is Z² = (hc/λR)(1/n² - 1/4)⁻¹, where Z represents the nuclear charge. Through trial and error, the user determined that substituting n values of 3, 4, and 5 yields a consistent nuclear charge of Z=6, indicating the element corresponds to carbon.

PREREQUISITES
  • Understanding of the Rydberg formula for hydrogen-like atoms
  • Familiarity with the concept of nuclear charge (Z)
  • Knowledge of the Balmer series and its significance in spectroscopy
  • Basic grasp of quantum mechanics and energy levels in atoms
NEXT STEPS
  • Study the derivation and applications of the Rydberg formula for various elements
  • Explore the Balmer series and its implications for hydrogen and hydrogen-like atoms
  • Investigate the concept of nuclear charge and its role in atomic structure
  • Learn about spectroscopy techniques used to measure atomic wavelengths
USEFUL FOR

Students and educators in chemistry and physics, particularly those focusing on atomic structure, spectroscopy, and the behavior of hydrogen-like atoms.

Kara386
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Homework Statement


These wavelengths are emitted by a hot gas:
18.226, 13.501, 12.054 (in nanometres)

Show that they are consistent with the Balmer series for a hydrogen-like atom.
Which element do they correspond to?

Homework Equations


Rearranged Rydberg formula for hydrogen-like atoms:
##Z^2 = \frac{hc}{\lambda R}(\frac{1}{n^2}-\frac{1}{4})^{-1}##

The Attempt at a Solution


Z is nuclear charge, that's really what I need to find to identify the element, so I rearranged the Rydberg formula to get the above expression.

The only way I can think of to solve this is by trial and error. So I tried subbing in ##n=3## and the first wavelength, and found that that corresponded to ##Z=6##, then ##n=4## and ##n=5## with the next two wavelengths respectively also gave ##Z=6##. But I'm not sure that really satisfies the condition 'show that they are consistent', because I've just guessed n and it happened to work. Is there a better way to solve this?
 
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Your approach is good.
 
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