Showing work done on gas in a reversible process

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SUMMARY

The discussion focuses on calculating the work done on an ideal gas during a reversible compression process where the pressure is defined by the equation P = AV. The gas is compressed from an initial volume Vi to a final volume Vf, which is half of Vi. The correct expression for the work done on the gas is derived using the integral W = ∫ P dV, leading to the conclusion that the work done is -3/8 nRTi. This solution emphasizes the importance of recognizing that the temperature varies during the process, making the application of W = nRT ln(Vf/Vi) inappropriate.

PREREQUISITES
  • Understanding of the ideal gas law and its applications
  • Familiarity with calculus, specifically integration techniques
  • Knowledge of thermodynamic processes, particularly reversible and adiabatic processes
  • Concept of degrees of freedom in thermodynamics
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  • Study the derivation of work done in adiabatic processes using W = ∫ P dV
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  • Explore the relationship between pressure, volume, and temperature in ideal gases
  • Investigate the concept of degrees of freedom and its effect on thermodynamic equations
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Students and professionals in thermodynamics, particularly those studying ideal gas behavior and reversible processes, as well as educators seeking to clarify concepts related to work done in gas systems.

Ryomega
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Homework Statement



Ideal gas initially at temperature Ti, Pressure Pi, Volume Vi is compressed reversibly down to half its original volume. Temperature of gas is varied during the compression so that

P = AV is always satisfied [where A is a constant]

Show that the work done on the gas is:

-\frac{3}{8}nRTi

Homework Equations



W = ∫ Pdv

W = nRT ln(\frac{Vf}{Vi})

W = A\frac{Vf-Vi}{1-\gamma}

\gamma = \frac{Cp}{Cv}=\frac{N+2}{N} where N is the degree of freedom (3 in this case)

The Attempt at a Solution



I gather that the solution is already in one of those equations and that I am probably being stupid. Yet everything I have tried so far does not get me to the solution.

From the problem I understand that the process is adiabatic since process is reversible and temperature changes to give:

\frac{P}{V}=const.

which I am confused on since:

PV^\gamma=const

I understand that this may be against the policy of this forum, but would anyone mind showing me how to arrive at this solution? I learn best from examples.

Thank you
 
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Hi Ryomega. The work done W=nRTln(\frac{Vf}{Vi}) doesn't apply here because the temperature isn't constant. So from W=∫PdV, and use P=AV in the integral from the initial volume of V to the final volume of V/2. You can workout what A is from the ideal gas equation.
 
Aha! I knew I was being stupid! I didn't think about the substitution. Thanks a LOT!
 

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