Solve the Mystery: Pure Silicon Resistivity at Zero

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The discussion centers on the calculation of pure silicon's resistivity at zero, using the formula for temperature dependence of resistivity. The user calculated that resistivity would drop to zero at 307 K, based on a negative temperature coefficient of resistivity. However, others pointed out that the linear approximation used is only valid over a limited temperature range and is not suitable for semiconductors like silicon, which behave differently than metals. The equation referenced is more applicable to materials with a positive temperature coefficient, leading to confusion about its application to silicon. The consensus emphasizes the need for a more appropriate model for semiconductors to accurately describe resistivity changes with temperature.
kahwawashay1
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I noticed that the temperature coefficient of resistivity of pure silicon is a rather high negative number, so just out of curiosity I wanted to see at what temp the resistivity would drop to zero.

The formula is ρ-ρ0 = ρ0α(T-T0)
where ρ is the final resistivity, ρ0 is the reference resistivity, α is the temperature coefficient of resistivity, T is the final temp and T0 is the reference temp

My book gives the α at a reference temp of 293 K. At this temp, ρ0 is 2.5*10^3 and α is -70*10^-3. Therefore, if we set the final resistivity (ρ) to 0:

-ρ0 = ρ0α(T-T0)
-1/α = T-T0
T = -1/α + T0
= -1/(-70*10^-3) + 293
= 307 K

I have been told that this can't possibly be right, but no one will tell me exactly why.
I have been told that what I'm doing wrong is "assuming that resistivity does not change with temp", even though I obviously am taking that into consideration, since I am using an equation that says approximately how resistivity changes with temp.
I have also been told that the linear approximation equation I am using holds only for a limited range with respect to the reference temp, and I also know that it won't hold for huge temps, but 307 K is not too far from room temp. (and actually, according to my book, this equation holds "over a rather large temperature range")

Could someone please point out exactly what I am doing wrong?
There must be something wrong because I don't think silicon is a conductor at some 35-ish degrees Celsius..
 
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The equation you have quoted is a version of the variation of resistance/resistivity equation for a material ( metal) with a + ve temp coefficient ( resistance increases with temp)

R = Ro(1+αt) ( t is temp in C)
This equation is only an approximation for reasonably low temps and shows that resistance increases uniformly with temp.
A fuller form of the equation is R = Ro(1+αt+βt^2+...)
one thing for sure... It is not the equation to use for semiconductors ( silicon)
 
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