Solving Flexible Balloon H2S Gas Problem: Q, ΔU, W & V

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Homework Help Overview

The discussion revolves around a problem involving the thermodynamic behavior of hydrogen sulfide gas (H2S) contained in a flexible balloon. The gas undergoes two distinct expansions: an isobaric expansion followed by an adiabatic expansion, with specific parameters provided for the initial conditions and properties of the gas.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • Participants discuss the relationship between internal energy and temperature for an ideal gas, with some attempting to calculate the change in internal energy based on temperature changes. Questions arise regarding the implications of the temperature returning to its initial value and how that affects internal energy and work done.

Discussion Status

The discussion is ongoing, with participants exploring various interpretations of the relationships between heat, work, and internal energy. Some have proposed that the change in internal energy may be zero due to the temperature returning to its initial value, while others are still working through the implications of this on the total work done and the final volume.

Contextual Notes

Participants are navigating the constraints of the problem, including the specific heat capacities and the ideal gas assumptions. There is a focus on ensuring that the calculations align with the thermodynamic principles governing adiabatic processes.

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Homework Statement



A flexible balloon contains 0.375 mol of hydrogen sulfide gas H2S. Initially the balloon of H2S has a volume of 6750 cm^3 and a temperature of 29.0 C. The H2S first expands isobarically until the volume doubles. Then it expands adiabatically until the temperature returns to its initial value. Assume that the H2S may be treated as an ideal gas with C_p = 34.60 J/mol*K and gamma = 4/3.

a) What is the total heat Q supplied to the H2S gas in the process?

b) What is the total change in the internal energy Delta U of the H2S gas?

c) What is the total work W done by the H2S gas?

d) What is the final volume V?



The Attempt at a Solution



For part A, I found Q = 3290J, which is the right answer.
For part B, I know that Delta U = nCv*Delta T, but I can't come out with the right answer. I'm sure once I find part B, the others will be much easier.
 
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they ask for the total change in the internal energy. For an ideal gas the internal energy only depends on the temperature.
 
So if the change in temperature is 302K, that's the change in internal energy?
 
gmarc said:
So if the change in temperature is 302K, that's the change in internal energy?
In the second phase the temperature returns to its initial value.
 
Ok, so the change in internal energy is equal to zero, and the total work done is just equal Q, the heat supplied. Now I just can't find the final volume in m^3
 
you know that P V^{\frac {C_p}{C_v}} = constant for adiabatic expansion?
 

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