Solving Number of Molecules for Entropy of 1.181x10^-12 J/K

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SUMMARY

The discussion focuses on calculating the number of molecules corresponding to an entropy of 1.181x10^-12 J/K using the formula S = k*ln(W). The Boltzmann constant (k) is specified as 1.38 x 10^-23 J/K. The initial attempt incorrectly assumed the number of microstates (W) as 2, leading to an erroneous calculation of approximately 3.242e13. The correct approach involves treating W as an unknown and solving for it to determine the number of molecules in the solid sample.

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Homework Statement


Suppose a compound could point in any two directions in the solid and still have the same energy. How many molecules would there be if the total entropy of a solid sample of this compound was 1.181x10^-12 J/K?

Homework Equations


My plan that failed -

S = k*ln(W),
where S is entropy
k is Boltzmann constant = 1.38 x 10-23 (J/K) or equivalent to (Universal Gas Constant 8.314/Avogadro's number 6.02 x 1023 molecules/mol)
W is the number of microstates

The Attempt at a Solution


1.181x10^-12 J/K = (8.314/ x 6.02*1023)*(ln(2)), I put 2 in ln(2) because I thought the question stated the total microstates when it said "...point in any two directions".

I solved for x and got 3.242e13 which is wrong.
 
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It would be 2 microstates if there were just 1 molecule. With many molecules, there are many many possible combinations of their orientations.

Treat W as an unknown, and solve for it. Once you have W, the final step will be to figure out how many molecules.
 

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