Some questions about naming conventions for ethers

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SUMMARY

The discussion focuses on naming conventions for cyclic ethers, specifically highlighting the trivial names such as ethylene oxide (C2O) and tetrahydrofuran (C4O). The user proposes a systematic naming approach for cyclic ethers, exemplified by 1,3,5-trioxycyclohexane for a structure with three oxygen and three carbon atoms. Additionally, the user mentions the importance of counting from the nearest oxygen atom in compound names, as seen in 2,3-benzo-1,3-dioxycycloheptane. The conversation emphasizes the distinction between trivial and IUPAC names in organic chemistry.

PREREQUISITES
  • Understanding of IUPAC nomenclature for organic compounds
  • Familiarity with cyclic ether structures
  • Basic knowledge of organic chemistry functional groups
  • Experience with naming conventions in chemical compounds
NEXT STEPS
  • Research IUPAC naming conventions for cyclic compounds
  • Study the properties and applications of tetrahydrofuran (THF)
  • Learn about the synthesis and reactivity of cyclic ethers
  • Explore advanced topics in organic chemistry related to ether nomenclature
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Chemistry students, organic chemists, and professionals involved in chemical nomenclature and synthesis will benefit from this discussion.

espen180
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First, I am wondering about naming conventions for cyclic ethers.

I have found
[tex]C_2O[/tex] : Ethylene oxide
[tex]C_4O[/tex] : Tetrahydrofuran

But (I think) these are trivial names.

I think I found a system where for example a cycle of three O-atoms and three C-atoms in C-O-C-O... fashion becomes 1,3,5-trioxycyclohexane.

Also, in compounds, we count from the O-atom closest to the bond between the compounds, like in 2,3-benzo-1,3-dioxycycloheptane?

Can anyone confirm this, eventually contribute additional useful rules related to this?

Thanks in advance.
 
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Names like THF are like calling H2O water instead of hydrogen hydroxide (pretty much). These aren't IUPAC names, so you're right, they're trivial. I'm not great with cyclical naming, so I'll leave the second part to someone who's a little more experienced in organic chemistry.
 

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