Standard Finite Well Problem (Solve without symmetry)

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SUMMARY

The discussion focuses on solving the energy eigenvalue problem for a finite square well without relying on symmetry assumptions. The potential outside the well is V0, while it is 0 inside the well, leading to a piecewise wave function defined as ψ(x)={ A e^(q x) for x<-a; C Sin(kx) + D Cos(kx) for -aa. The user seeks guidance on deriving transcendental equations from continuity conditions at the boundaries x=a and x=-a without invoking symmetry, which typically simplifies the process by separating the wave function into even and odd components.

PREREQUISITES
  • Understanding of Schrödinger's Equation and its application in quantum mechanics.
  • Familiarity with boundary conditions and normalization of wave functions.
  • Knowledge of piecewise functions and their continuity properties.
  • Concept of transcendental equations and their significance in quantum mechanics.
NEXT STEPS
  • Research the derivation of boundary conditions for finite square wells in quantum mechanics.
  • Study the mathematical techniques for solving piecewise-defined functions.
  • Explore methods for deriving transcendental equations from continuity conditions.
  • Learn about the implications of even and odd wave functions in quantum systems.
USEFUL FOR

Students and educators in quantum mechanics, particularly those tackling finite square well problems without symmetry assumptions, as well as researchers interested in advanced quantum mechanics concepts.

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Homework Statement



Solve the energy eigenvalue problem for the finite square well without using the symmetry assumption and show that the energy eigenstates must be either even or odd.

Homework Equations



The finite well goes-a to a and has a potential V0 outside the box and a potential of 0 inside the box.

The Attempt at a Solution



I understand the book's solution of the problem which utilizes symmetry but am a little stuck as to how to proceed without it. Basically, one plugs the potentials into the energy eigenvalue equation (Schrödinger's Equation) and solves to find ψ(x)={ A e^(q x)+ B e^-(q x) for x<-a; C Sin(kx) + D Cos(kx) when -a<x<a; F e^(q x)+G e^-(q x) for x>a.

Once this ψ is found (it's a piecewise function) boundary conditions reveal that B=F=0 in order for the function to be normalizable. This gives ψ={A e^(q x for x<-a; C Sin(kx) + D Cos(kx) when -a<x<a; G e^-(q x) for x>a.

At this point the book invokes symmetry to split the function into ψeven which carries the Cos term and ψodd which carries the Sin term. It then proceeds to derive the transcendental equations.

I am uncertain as to how to get to the transcendental equations without invoking the symmetry argument.

Any help that can be offered would be appreciated.

Thanks!
 
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What equations do you get from requiring continuity of ##\psi## and its derivative at x=a and x=-a?
 

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