SuperIonic Water: A New Form of Matter?

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Discussion Overview

The discussion revolves around the concept of superionic water, a state of matter formed under high pressure and temperature, characterized by a rigid lattice of oxygen atoms with positively charged hydrogen nuclei moving through it. Participants explore its properties, implications, and the terminology associated with it, particularly in relation to traditional definitions of water.

Discussion Character

  • Exploratory
  • Debate/contested
  • Conceptual clarification

Main Points Raised

  • Some participants express confusion about the classification of superionic water as "water" when it lacks H2O molecules in a traditional sense.
  • Others argue that similar naming conventions exist in chemistry, such as referring to salt in seawater despite dissociation of NaCl into Na+ and Cl– ions.
  • A participant reflects on their understanding of ionic dissociation in solutions, suggesting that Na+ and Cl– ions remain significantly bonded in water, despite being represented as separate in chemical equations.
  • There is a mention of the potential properties of superionic water, such as being a good conductor and possibly acting as a strong acid.
  • Questions are raised about the degree of dissociation in superionic water compared to traditional aqueous solutions.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the classification of superionic water or the implications of its properties. Multiple competing views regarding the terminology and understanding of dissociation remain present throughout the discussion.

Contextual Notes

Participants express uncertainty regarding the definitions and implications of dissociation in both superionic water and traditional salt solutions. There are references to chemical equilibrium equations and the nature of bonding in solutions that remain unresolved.

BillTre
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Not sure where this might best be located. This is not a question, more like a show and tell.

I read about superionic water in a NY Times article here.
Never heard of it before.
Formed at high pressure and temperature, it is described as simultaneously solid and liquid, and as "rigid lattice of oxygen atoms through which positively charged hydrogen nuclei move".
It may exist in Uranus or Neptune.
 
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BillTre said:
Formed at high pressure and temperature, it is described as simultaneously solid and liquid, and as "rigid lattice of oxygen atoms through which positively charged hydrogen nuclei move".
How can it be called water when the H2O molecules are not there.
 
What's in a name? That which we call a rose. By any other word would smell as sweet.
(Quack!)
 
Baluncore said:
How can it be called water when the H2O molecules are not there.
We do something similar when we say that there is salt in seawater even though the NaCl molecules are well and thoroughly dissociated.
 
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Nugatory said:
We do something similar when we say that there is salt in seawater even though the NaCl molecules are well and thoroughly dissociated.
I used to believe that Na+ and Cl were quite independent in a solution. But I was corrected by an academic chemist who explained that it is only in the chemical equilibrium equation that they are shown as being totally separate. Only the temporarily dissociated reactive molecule is represented in that equation.
Since then I have been under the impression that when NaCl dissolves in water, the Na+ and Cl remain significantly bonded while being supported in the water, with each NaCl molecule being independent of other NaCl molecules.
Likewise, most molten NaCl molecules remain bonded, but are too hot to crystallise, molten NaCl is not a plasma.

In a similar way, only about one millionth of the water solvent is dissociated. It is still H2O.
Superionic "water" is described as "rigid lattice of oxygen atoms through which positively charged hydrogen nuclei move". That is total dissociation.
How dissociated is “well and thoroughly”?

For; NaCl(aq) <=> Na+(aq) + Cl(aq); does anyone have any reference to the degree of dissociation.
 
Seems like it should be a good conductor.
And a strong acid ("molecular acid" like in the Alien's blood?)?
 
Baluncore said:
I used to believe that Na+ and Cl were quite independent in a solution. But I was corrected by an academic chemist who explained that it is only in the chemical equilibrium equation that they are shown as being totally separate. Only the temporarily dissociated reactive molecule is represented in that equation.
Since then I have been under the impression that when NaCl dissolves in water, the Na+ and Cl remain significantly bonded while being supported in the water, with each NaCl molecule being independent of other NaCl molecules.
Likewise, most molten NaCl molecules remain bonded, but are too hot to crystallise, molten NaCl is not a plasma.

In a similar way, only about one millionth of the water solvent is dissociated. It is still H2O.
Superionic "water" is described as "rigid lattice of oxygen atoms through which positively charged hydrogen nuclei move". That is total dissociation.
How dissociated is “well and thoroughly”?

For; NaCl(aq) <=> Na+(aq) + Cl(aq); does anyone have any reference to the degree of dissociation.
There's always someone who knows more than me! (And several others too, in this case.) That argument certainly makes sense though.
 

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