The decrease in volume requires the surroundings do 7.6 J of work on the gases

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Discussion Overview

The discussion revolves around calculating the change in internal energy of gases during a chemical reaction involving hydrogen and ethylene, specifically focusing on the work done by the surroundings and the heat produced in the reaction. The context includes theoretical application of thermodynamic principles.

Discussion Character

  • Technical explanation
  • Mathematical reasoning
  • Homework-related

Main Points Raised

  • Post 1 presents a scenario involving the reaction of gases and introduces the need to calculate the change in internal energy using the formula ΔU = Q + W, where Q is the heat energy and W is the work done.
  • Post 1 questions the interpretation of the "7.6 J of work" and its role in the calculation.
  • Post 2 suggests applying the work-energy theorem and prompts clarification on whether the 7.6 J is energy being added or removed, indicating the need to adjust energy calculations accordingly.
  • Post 3 provides a calculation based on the earlier discussion, showing a change in internal energy of -302.4 J.
  • Post 4 expresses agreement with Post 3's calculation.
  • Post 5 acknowledges the confirmation of the calculation with a positive response.

Areas of Agreement / Disagreement

Participants generally agree on the approach to the calculation, but there is some uncertainty regarding the interpretation of the work done (7.6 J) and its impact on the energy calculations.

Contextual Notes

There is a lack of clarity on the assumptions regarding the sign of the work done and how it affects the overall energy balance, which remains unresolved.

FLgirl
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1. Reacting 50 mL of H2(g) with 50 mL of C2H4(g) produces 50 mL of C2H6(g) at 1.5 atm. If the reaction produces 3.1 x 10^2 J of heat and the decrease in volume requires the surroundings do 7.6 J of work on the gases, what is the change in internal energy of the gases?




2. Change in Internal Energy = Q(heat energy) + W(work)
Work = - P x (change in volume)




3. I know how to apply these equations but have no idea about the " 7.6 J of work" part.
 
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Thanks tiny tim :) This is what I got:

(-310 J) + (7.6J)
= 302.4 J = -3 x 10^2 J
 
looks right :smile:
 
sweet, thanks
 

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