Herman Trivilino
Science Advisor
Gold Member
- 3,648
- 1,677
I think that such a definition is beyond what I can put in a forum post. It wouldn't do justice to the question asked, and would just result in an extended back and forth discussion. It is instead something to be found in a textbook or a published article. You can find good definitions in many of the college-level introductory physics textbooks written in the last 15-20 years.jbriggs444 said:I think that generalized work (a transfer of mechanical energy without a transfer of mass) is the same thing as thermodynamic work, but am still awaiting your definition.
I refer you to, and strongly recommend, the paper by Arnold B. Arons that starts on page 1063 of the American Journal of Physics [Am. J. Phys. 67 (12), December 1999]. If you can't get access to the article let me know and I can send you the PDF via private message.
Here is an excerpt from that paper that may answer your question:
How must work be calculated? Experience shows
that the useful operational definition of work must be developed
along the lines discussed by P. W. Bridgman in his
careful, insightful, and thorough analysis in The Nature of
Thermodynamics:
Turn now to an examination of the W of the First Law.
This W means the total mechanical work received by the
region inside the boundary from the region outside [or
delivered to the region outside from the region inside]. As
in the case of [heat transfer] Q, this work is done across
the boundary, and the evaluation of W demands the posting
of sentries at all points of the boundary, and the summing
of their contributions. In the simple cases usually
considered in elementary discussions, the work received
by the inside from the outside is of the simple sort typified
by the motion of stretched cords or of simple linear piston
rods. Our sentry can adequately report this sort of thing in
terms of finite forces acting at points and finite displacements.
In general, however, there will be contact of the
material outside over finite regions of the boundary, and
we become involved in the stresses and strains of elasticity
theory.
[Bridgman goes on to mention the ‘‘infelicities" that result
when we apply the notion of work to the sliding of two
bodies on each other with friction.]
To emerge as a conserved quantity, work must be calculated
by summing the product of forces and their corresponding
displacements over the periphery or boundary of the system
which has been defined. For example, for a compressed
spring, we must calculate the integral over the displacement
of the end of the spring and not over the displacement of its
center of mass.
Last edited: