Thermochromatic liquid crystals, how do they change color?

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SUMMARY

Thermochromatic liquid crystals, specifically cholesteric (or chiral nematic) liquid crystals, change color based on temperature due to their unique alignment and pitch. When the pitch matches the wavelength of red light, the crystals reflect red light while allowing other wavelengths to pass through. This phenomenon is influenced by the layered structure of the liquid crystals and their interaction with light, including reflection and phase changes. Understanding these principles clarifies the color-changing behavior observed in mood rings and LC thermometers.

PREREQUISITES
  • Cholesteric liquid crystal phase
  • Light wavelength and pitch relationship
  • Polarization of light
  • Phase change in optics
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  • Research the properties of cholesteric liquid crystals in detail
  • Explore the principles of light polarization and its effects on color perception
  • Study the interaction of light with liquid crystals, focusing on reflection and absorption
  • Investigate applications of thermochromatic liquid crystals in technology and design
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Students and professionals in materials science, optical engineering, and anyone interested in the practical applications of thermochromatic liquid crystals in products like mood rings and thermometers.

Coolcrab
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If you look at liquid crystals in things like moodrings and LCthermometers then you will notice that they can change color when heated.

Now I have looked on the internet and found that it has to do with the The cholesteric (or chiral nematic) liquid crystal phase, where they align with each other in layers but are slightly tilted across layers. Example:
image006.gif


I also know that they reflect the light which has the wavelength of a full rotation of the crystals, this being called the "pitch". (see pic)

So if they rotate at such an angle that they make a full rotation in P = lambda Red, then it will look red.

But I do not know why. If I look at this picture, then it looks like a polariser that goes in all directions:
http://plc.cwru.edu/tutorial/enhanced/files/lc/phase/Graphics%5Cschem.BMP Which would cansel out all the light, and not reflect any.

So can anyone tell me what's going on here?
 
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I don't think that it has to do with reflection of the back, as they say that that's often black to absorb everything that comes trough.
So it has to reflect all red light, while letting trough all the other light. But I don't see why or how.

And yea I, saw that source :P
 
I now know that the poleriser would not cansel out all the light, but rather repolerise/absorb a bit.
But I still don't get why red light would be reflected, while the rest is let trough.

Edit: red light in the case the the pitch has the length of red light's wavelength
 

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