Thermodynamics problem -- Find the mass of water that vaporizes

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SUMMARY

The problem involves calculating the mass of water that vaporizes when 3.02 kg of mercury at 223 °C is added to 0.347 kg of water at 83.4 °C. The relevant equations include the heat transfer equation mc∆t and the relationship between the heat lost by mercury and the heat gained by water. The final calculation for the mass of vapor resulted in 540.6 grams, but the user struggled with determining the correct change in temperature and constants involved. The discussion emphasizes the importance of accurate temperature values and constants for solving thermodynamic problems.

PREREQUISITES
  • Understanding of thermodynamic principles, specifically heat transfer.
  • Familiarity with the specific heat capacities of mercury and water.
  • Knowledge of the concept of latent heat of vaporization.
  • Ability to manipulate equations involving multiple variables and subscripts.
NEXT STEPS
  • Review the concept of specific heat capacity and its application in thermodynamic calculations.
  • Learn about latent heat of vaporization and its significance in phase changes.
  • Practice solving heat transfer problems involving multiple substances and temperature changes.
  • Explore the use of thermodynamic tables for constants related to water and mercury.
USEFUL FOR

Students studying thermodynamics, educators teaching heat transfer concepts, and anyone involved in physics or engineering disciplines requiring heat calculations.

Alice7979
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Homework Statement



Find the mass of water that vaporizes when 3.02 kg of mercury at 223 °C is added to 0.347 kg of water at 83.4 °C.

Homework Equations


Mercury Q = Water Q + Water mL
mc∆t= mc∆t + mL

The Attempt at a Solution


mass of vapor = ((3.02)(140)(223-tfinal) - (4186)(.347)(change in temperature))/100

I don't know the change in temperatures for sure, all the ones i have tried are wrong.
 
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Alice7979 said:
all the ones i have tried are wrong.
It’s not a guessing game! The water will heat up to boiling temperature, then any additional energy will not raise the temperature (it instead goes into vaporization).

Alice7979 said:
mc∆t= mc∆t + mL
This equation could solve the problem, if you have the correct subscripts (there are two c’s, two ∆t‘s, and three masses involved).
 
Alice7979 said:

Homework Statement



Find the mass of water that vaporizes when 3.02 kg of mercury at 223 °C is added to 0.347 kg of water at 83.4 °C.

Homework Equations


Mercury Q = Water Q + Water mL
mc∆t= mc∆t + mL

The Attempt at a Solution


mass of vapor = ((3.02)(140)(223-tfinal) - (4186)(.347)(change in temperature))/100

I don't know the change in temperatures for sure, all the ones i have tried are wrong.
Although not state explicitly, this assumes that the water is in contact with air at 1 atm, so the evaporation takes place at 100 C (the final temperature).
 
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Nathanael said:
It’s not a guessing game! The water will heat up to boiling temperature, then any additional energy will not raise the temperature (it instead goes into vaporization).This equation could solve the problem, if you have the correct subscripts (there are two c’s, two ∆t‘s, and three masses involved).

mass of vapor = ((3.02)(140)(223-100) - (4186)(.347)(100-92.8))/100 = 540.6

That's what i tried but i still get it wrong, is it the change in temperature i have wrong?
 
How much heat does the mercury give up in cooling from 223 to 100 C? How much of this heat must be used to heat the water up from 92.8 C to 100 C? The rest of the heat is used to vaporize some of the water.
 
Alice7979 said:
mass of vapor = ((3.02)(140)(223-100) - (4186)(.347)(100-92.8))/100 = 540.6

That's what i tried but i still get it wrong, is it the change in temperature i have wrong?
It would be nice, in the future, if you provided all relevant constants, so that I don’t have to look up everything.

It looks like you’re saying the energy of vaporization is 100 J/kg ?
Also I thought it started at 83.4 degrees not 92.8?
 
Nathanael said:
It would be nice, in the future, if you provided all relevant constants, so that I don’t have to look up everything.

It looks like you’re saying the energy of vaporization is 100 J/kg ?
Also I thought it started at 83.4 degrees not 92.8?
Yes, I did have that wrong but I found it. Thanks
 

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