TiO2 Band Gap Energy: Direct vs. Indirect

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SUMMARY

The discussion clarifies that titanium dioxide (TiO2) can exhibit both direct and indirect band gap energies depending on its crystalline structure and the specific transitions involved. It is established that a single semiconductor like TiO2 may possess characteristics of both types of band gaps, which can lead to confusion in literature. The differences in band gap energy are also influenced by whether the material is in bulk form or as a thin film, particularly structured thin films. This nuanced understanding is critical for applications in semiconductor physics and materials science.

PREREQUISITES
  • Understanding of semiconductor physics
  • Familiarity with band gap energy concepts
  • Knowledge of crystalline structures in materials science
  • Experience with thin-film technology and its properties
NEXT STEPS
  • Research the differences between direct and indirect band gap semiconductors
  • Explore the impact of crystalline structure on electronic properties of TiO2
  • Investigate the properties of TiO2 in bulk versus thin-film applications
  • Review recent studies on TiO2 band structure and its implications in technology
USEFUL FOR

Materials scientists, semiconductor physicists, and engineers working with titanium dioxide in applications such as photovoltaics and photocatalysis will benefit from this discussion.

Doeroo
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When we say generally TiO2 band gap energy, is it meaning direct or indirect band energy?
Some papers show only direct BG or indirect BG or both. Is it right that one semiconductor has one of direct and indirect BG. I am a little bit confused.
 
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The following came up in a Google search for 'titanium dioxide band structure' (which also has some references listed):
http://www.tyndall.ie/research/electronic-theory-group/cm4105/bandstructs/TiO2_b.pdf

It's been a while since my semiconductor theory class, but the discrepancy could come from the different crystalline structures and/or different transitions. There will also be a difference between bulk and thin-film (especially structured ones) properties.

EDIT: And welcome to PhysicsForums!
 
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