Triple Point Water: Why Used for SI Thermodynamic Temp

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SUMMARY

The triple point of water, defined at 273.16 K and a partial pressure of 611.73 Pa, serves as the SI base unit for thermodynamic temperature due to its unique reproducibility under specified conditions. Unlike the ice point and boiling point, which vary with pressure, the triple point remains constant, making it a reliable reference. This unique characteristic allows for accurate calibration of temperature probes, ensuring consistency across measurements. The discussion emphasizes the importance of pressure stability when determining temperature at the ice point, highlighting the advantages of using the triple point for standardization.

PREREQUISITES
  • Understanding of thermodynamic temperature scales
  • Familiarity with the concept of the triple point
  • Knowledge of pressure and its effects on phase changes
  • Basic principles of temperature calibration techniques
NEXT STEPS
  • Research the properties and significance of the triple point of water in thermodynamics
  • Explore methods for calibrating temperature probes using the triple point
  • Study the effects of pressure on the boiling and freezing points of water
  • Investigate the historical context and development of SI units related to temperature
USEFUL FOR

Scientists, engineers, and educators in the fields of thermodynamics, metrology, and temperature measurement will benefit from this discussion, particularly those involved in standardizing temperature measurements and calibrating instruments.

gunparashar
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why triple point of water is used to define SI base unit of thermodynamic temperature even though for triple point we need to define both temperature (. 01) and pressure(partial pressure = 611.73 pa). this thing we can do with ice point and boiling point which is same when temperature and pressure is defined.
 
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The ice point and boiling point change depending on your pressure. The triple point does not.
 
The boiling point and freezing point of water depend on pressure. At higher pressure the boiling point moves up (higher temperatures) while the freezing point moves down. So boiling point and freezing point are not uniquely defined while the triplr point temperature is unique.
 
gunparashar said:
why triple point of water is used to define SI base unit of thermodynamic temperature even though for triple point we need to define both temperature (. 01) and pressure(partial pressure = 611.73 pa). this thing we can do with ice point and boiling point which is same when temperature and pressure is defined.

i think it is the other way around, isn't it. The triple point defines the temperature and pressure.

Reproducibility is the key.
Take a container of water and evacuate all the air so there is just liquid water and gas. Cool the container until some ice forms. You now have the triple point at the solid, liquid, gas interface and any temperature probe can be calibrated for 273.16 K.

With you method, one has to know the pressure beforehand for the ice point, as said above that can change with pressure. If the pressure is off, so is the temperature.

Luckily, at normal atmospheric temperature there is little difference. I believe it is 273.15K.
 

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