Trying to understand the Brillouin zone

In summary, the Brillouin zone is a concept used to describe the relationship between electron states and their wavevectors in a band structure. The different symbols on the bottom of the band structure diagram correspond to different points in the Brillouin zone. The Gamma point at the center of the Brillouin zone has a wavevector of K=0, but this does not mean that the electron at this point has no energy. The Gamma point appears twice on the bottom of the diagram because it represents both the origin of the Brillouin zone and the point where the wavevector points in opposite directions. As the magnitude of the wavevector increases, it must also point in a different direction, leading to different electron states. These states represent
  • #1
phrygian
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I am having a really hard time understanding how the Brillouin zone relates to electron states and have a couple of questions that might help clear it up for me.

For a band structure like this:

https://wiki.fysik.dtu.dk/gpaw/_images/silicon_banddiagram.png

I know that the different symbols on the bottom correspond to different points in the Brillouin zone. Gamma is the center of the Brillouin zone with K=0, so how can an electron with that wavevector have any energy? And why does Gamma appear on the bottom twice?

Do these diagrams mean that when an electrons wavevector increases in magnitude it also must point in a different direction? And what do these states mean, that the electrons are plane waves traveling in one direction?

Thanks a lot for the help, it would really be great to finally understand these concepts.
 
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  • #2
The wavevector only describes the variation of the phase going from elementary cell to elementary cell. But this does not exclude a variation of phase or more generally wavefunction (and accompanying kinetic energy) within an elementary cell. E.g. think about a crystal made up of helium atoms. The energy of the lowest band is approximately equal to that in a free helium atom irrespective of the phase (k vector) with which the wavefunctions of different atoms are superposed.
 

What is the Brillouin zone and why is it important in science?

The Brillouin zone is a concept in solid state physics that helps us understand the behavior of electrons in a crystal lattice. It is essentially a representation of the periodicity of the crystal structure and helps us predict the properties of materials. It is an important tool in understanding the electronic and optical properties of materials.

How is the Brillouin zone related to the reciprocal lattice?

The Brillouin zone is the first Brillouin zone of the reciprocal lattice. This means that it is the smallest unit cell in the reciprocal lattice that contains all the information about the crystal structure. It is the fundamental unit that allows us to describe the periodicity of the crystal.

What is the difference between the first Brillouin zone and other zones?

The first Brillouin zone is the smallest unit cell in the reciprocal lattice, while other zones (such as the second or third Brillouin zone) are larger unit cells that contain information about higher order diffractions. The first Brillouin zone is the most commonly used in calculations and analysis.

How can the Brillouin zone be visualized?

The Brillouin zone can be visualized as a three-dimensional shape in reciprocal space. In two dimensions, it can be represented as a hexagon or a square, depending on the crystal symmetry. In three dimensions, it can be represented as a polyhedron with multiple faces. There are also various mathematical representations of the Brillouin zone that can be used for calculations and analysis.

What is the significance of the Brillouin zone in band structure calculations?

The Brillouin zone is crucial in band structure calculations as it allows us to determine the allowed energy levels of electrons in a crystal lattice. By analyzing the structure of the Brillouin zone, we can predict the electronic properties of materials, such as conductivity and optical properties. It is a fundamental concept in understanding the behavior of electrons in solids.

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