Tunnel ionization rates; question on atomic units

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Homework Help Overview

The original poster is working on a Matlab script to evaluate tunnel ionization rates using the PPT model, referencing a specific paper for the rate equation. They express concerns about discrepancies in their results, which they suspect may stem from their understanding and application of atomic units for various parameters.

Discussion Character

  • Exploratory, Assumption checking

Approaches and Questions Raised

  • The original poster questions how to correctly apply atomic units to parameters such as ionization potentials, frequencies, and electric fields. They mention finding various conversion factors but remain uncertain about their correctness.

Discussion Status

Some participants have provided references to resources on atomic units, and the original poster has identified a potential misunderstanding regarding the units of the tunnel ionization rate. They are now considering the implications of this realization on their calculations and are seeking further clarification on their inputs.

Contextual Notes

The original poster has noted that they are using specific values for frequency, ionization potential, and electric field, which may not be in atomic units, leading to confusion in their calculations.

dnic12345
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Homework Statement



First of all, this is my first post here, so I apologize if I format things incorrectly.

I'm working on a Matlab script to evaluate the tunnel ionization rates via the PPT model given the correct set of input parameters. The rate equation I am using contains equations 1-11 of A. Talebpour, et al. "Semi-empirical model for the rate of tunnel ionization..." from Opcits Communications 163, (1999) 29-32.

The paragraph leading up to the formula gives "In this model the rate of the TI from a state of an atom with ionization potential Ei, quantum numbers l and m and effective charge Zeff, in a laser field with frequency w and peak electric field F, in atomic units is given by..."

My rate calculations are giving me answers that are many orders of magnitudes off and I think its due to my use of atomic units. I know I have l,m, and Zeff in my equations correct, but I am unsure on the ionization potentials, frequencies, and electric fields in atomic units. The values I have in other units are:

w = 2.8986e+014 Hz (1035 nm wavelength)
Ei = 15.58 eV (N2)
E-field = 1.5e10 V/m


Homework Equations



There are way too many to type out for this formula; my main question is about atomic units. See the above-referenced paper for the actual equations.

The Attempt at a Solution


I've read about atomic units meaning that many constants (like h, hbar, etc) are identically set to 1, but I can't see how to apply this in my situation. I have found several different conversion factors online, but I can't convince myself that any of them are right.

If anyone is familiar with using atomic units in situations like this, please help!

Thanks
 
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Yea, I read through that and a number of other pages/pdfs. I did end up using values that are identical to what's on the wikipedia page. I believe I found my problem: the conglomeration of the eqs 1-11 spits out the tunnel ionization rate that I assumed to be in units of Hz. It makes more sense for the TI rate to be atomic units, given that all the inputs are in AU. When I convert the rate I calculate from AU to Hz, I get rates that are much closer to the reference values I have.

Now I think my work is just to make sure I have input and evaluated everything else correctly. I did use an approximation to an infinite sum that may be the key to my error.

Thanks for the response.
 
No problem, and good luck.
 

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