Understanding Limiting Reagents and Pressure Calculations in Gas Reactions

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SUMMARY

The discussion centers on calculating the final pressure in a gas reaction involving ammonia (NH3) and hydrochloric acid (HCl) in a 2.00 L flask at 25°C. The participants determined that HCl is the limiting reagent due to the 1:1 stoichiometric ratio in the reaction forming ammonium chloride (NH4Cl). To find the final pressure, it is essential to subtract the moles of the consumed gas from the total moles before applying the ideal gas law, as the solid product NH4Cl does not contribute to the gas pressure.

PREREQUISITES
  • Understanding of stoichiometry in chemical reactions
  • Knowledge of the ideal gas law (PV=nRT)
  • Familiarity with limiting reagents in chemical equations
  • Basic concepts of gas behavior at standard temperature and pressure
NEXT STEPS
  • Study the ideal gas law applications in chemical reactions
  • Learn about calculating limiting reagents in various chemical equations
  • Explore the effects of temperature and volume on gas pressure
  • Investigate the properties of solids formed in gas reactions
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Chemistry students, educators, and professionals involved in chemical engineering or laboratory work who need to understand gas reactions and pressure calculations.

Lancelot59
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NH3(g) + HCl(g) --> NH4Cl(s)

A 2.00 L flask containing 5.00 g of NH3 is connected to a 2.00 L flask containing 5.00 g of HCl. When the stopcock between the two flasks is opened the gases react until one of them is completely consumed. What is the final pressure in the apparatus when the reaction is complete? The temperature of the system is 25oC.

Well I found that HCl was the limiting reagent. I figured that since the equation is a 1:1 ratio I could just set the mols of NH4Cl as the mols of HCl and solve for the pressure using the ideal gas law.

Apparently there is another step, where I have to subract the mols of the two gasses, and then use THAT value in the gas law.

What is going on here? How is that value the number of mols in the NH4Cl?
 
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NH4Cl(s). Its volume is so small that it doesn't count.

--
 
I see now. Thanks. Wish me luck on the test today.

I really should've studied more. My other courses drove this test out of my head entirely.
Dumbass powers activate!
 

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