Using density to find the % composition of an alloy

In summary, the conversation discusses the densities of tin and lead and their composition in plumber's solder. The conversation includes an attempt at solving for the composition, with the book providing a different answer due to the use of weight percent and atomic percent.
  • #1
Kushal
438
1

Homework Statement



The densities (at 25*C) of tin and lead are 7.3 g/cm3 and 11.3 g/cm3 respectively. Plumber's solder is an alloy of tin and lead and has a density of 9.7 g/cm3.

Estimate the composition by mass, of the two metals in this solder.

Homework Equations





The Attempt at a Solution



i assumed the % composition of lead to be X%. so % composition of tin is (100 - X)%.
using [(X*11.3)/100] + [((100-X)*7.3)/100] = 9.7

i got % lead as 60% and % tin as 40%.

but the answers from the book are 30.1% for tin and 69.9% for lead.

any help!
 
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  • #2
Amount fractions can be measured in weight percent (wt%) or atomic percent (at%), so just writing "%" is ambiguous. Perhaps this explains the difference.
 
  • #3



Your approach is correct, but there may have been a mistake in your calculation. Here is the correct calculation:

Let X = % composition of lead, then (100-X)% is the % composition of tin.

To find the density of the alloy, we can use the formula:

Density = (Mass of lead * Density of lead) + (Mass of tin * Density of tin)

Substituting the values given in the problem, we get:

9.7 g/cm3 = (X * 11.3) + ((100-X) * 7.3)

Solving for X, we get:

X = (9.7 - 7.3) / (11.3 - 7.3) = 2.4 / 4 = 0.6 = 60%

Therefore, the % composition of lead is 60% and the % composition of tin is (100-60) = 40%. The book's answer of 30.1% for tin and 69.9% for lead is incorrect. It is possible that there was a mistake in the book or in the given data.
 

1. What is density and how is it related to percent composition?

Density is a measure of how much mass is contained in a given volume of a substance. It is related to percent composition because the density of a substance is determined by the types and amounts of elements present, which can be used to calculate the percent composition of the substance.

2. How do you calculate percent composition using density?

To calculate the percent composition of a substance using density, you first need to determine the mass and volume of each component in the substance. Then, divide the mass of each component by the total mass of the substance and multiply by 100 to get the percent composition.

3. Can density be used to determine the composition of any alloy?

Density can be used to determine the percent composition of an alloy as long as the individual densities of the components are known. If the alloy is made up of elements with unknown densities, other methods such as chemical analysis may be necessary.

4. What are the limitations of using density to find percent composition?

Using density to find percent composition is limited by the accuracy of the density measurements and the assumption that the density of each component remains constant throughout the alloy. Any impurities or variations in composition can affect the accuracy of the results.

5. Are there any other methods for determining percent composition besides using density?

Yes, there are other methods for determining percent composition such as chemical analysis, spectroscopy, and mass spectrometry. These methods may be more accurate for complex alloys or those with unknown densities.

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