Validity of Two-Fermion System Wavefunction with Quantum Numbers a and b

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SUMMARY

The two-body wavefunction for a two-fermion system, represented as $$\psi(1,2) = \phi_a(1) \phi_a(2) - \phi_b(1) \phi_b(2) + \phi_a(1) \phi_b(2) - \phi_b(1) \phi_a(2)$$, is not a valid description of the system. The wavefunction must be antisymmetric under the interchange of particles, which is a fundamental requirement for fermions. The correct form should satisfy the condition $$\psi(1,2) = -\psi(2,1)$$, which this wavefunction does not fulfill.

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  • Knowledge of antisymmetry in the context of particle interchange.
  • Basic grasp of quantum numbers and their significance in quantum states.
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Students and researchers in quantum mechanics, particularly those focusing on fermionic systems and wavefunction properties, will benefit from this discussion.

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Homework Statement


Is the statement ”Given a two-fermion system, and two orbitals φ labeled by quantum numbers a, b, the two-body wavefunction (1,2 represent the particle variables)

$$\psi(1,2) = \phi_a(1) \phi_a(2) - \phi_b(1) \phi_b(2) + \phi_a(1) \phi_b(2) - \phi_b(1) \phi_a(2) $$

correctly describes a possible state of the system” true or false ? Explain your answer

Homework Equations


I think this should be done by arguing so so relevant equations.

The Attempt at a Solution


There's a few of these problems with different wave functions. I'm not sure how to approach these problems.

Maybe by noticing that input (1,2) as not consistent to $\phi_a$ and $\phi_b$, respectively and can hence not describe a quantum state?
 
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The wavefunction of a fermionic system must be antisymmetric in the interchange of fermions, in your case the wavefunction should satisfy
$$
\psi(1,2) = -\psi(2,1).
$$
You just need to check whether the above relation is satisfied.
 
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Thank you!
 

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