Vapor pressure of Water calculation

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Discussion Overview

The discussion revolves around calculating the vapor pressure of water at a temperature of 43.0°C, given a total pressure of 758.3 torr. Participants explore the use of equations related to vapor pressure and seek clarification on the pressure of air at the specified temperature.

Discussion Character

  • Technical explanation
  • Mathematical reasoning
  • Homework-related

Main Points Raised

  • One participant proposes using the equation P(water) = P(total) - P(air) to calculate the vapor pressure.
  • Another participant questions how to determine the pressure of air (P(air)) at 43°C and mentions the need for the saturation pressure of water vapor at that temperature.
  • A participant expresses confusion about finding the air pressure at 43°C and inquires if there is a standard definition for it.
  • One participant notes that the total pressure of 758.3 torr is less than the standard pressure of 760 torr, which raises questions about the expected values at 43°C.

Areas of Agreement / Disagreement

Participants do not reach a consensus on how to find the pressure of air at 43°C, indicating that multiple views and uncertainties remain regarding the calculation of vapor pressure.

Contextual Notes

There is uncertainty regarding the standard air pressure at a given temperature and the saturation pressure of water vapor at 43°C, which may affect the calculations.

jKotha
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Ok, I need to calculate the vapor pressure of water.

All the information I am given is that the temp is 43.0 C, and I know the total pressure of the system is 758.3 torr.

Is there anyway I can calculate this using the Pwater = Ptotal - Pair equation?
There is also another equation that I have, but it is quite confusing for me. It is ln P = -(H/R)(1/T) + ln A

PLEASE HELP! Thanks guys

Jkotha
 
Last edited:
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If air is covering the water, then the gas phase contains air and water vapor, therefore P(water vapor) = P(total) - P(air).

Then what is the pressure of air at 43°C? For interest sake, what is the saturation pressure of water vapor at 43°C?
 
still not gettin it..

Ok i know that Ptotal = Pair + Pwater..

but... How do I know what Pair is at 43 C? That is the problem. Is there some standard definition of the pressure of air at a given temperature? I'm not sure... If I had that information it would make this problem a snap.

thanks,
jkotha
 
I thought I could find it online, but that doesn't seem to be easy.

I'll look in some thermo books, but that will have to wait until morning.

The interesting thing is that the total pressure of 758.3 torr is less than standard pressure for 760 torr, which I would expect for 43°C.

See if this helps - http://ww2010.atmos.uiuc.edu/(Gh)/guides/mtr/cld/dvlp/rh.rxml
 
Last edited:

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