Vibrational relaxation through electron-hole pairs

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In summary, when a molecule comes in contact with a metal surface, there are two channels that play a role in vibrational relaxation: the Phonon channel and the electron-hole pairs in the metal. While there is the possibility of photon emission from the molecule, the main interaction is through the Coulomb field affecting the electron-hole pairs. This is sometimes referred to as the "Fano problem," but it is not considered a dissipative channel. There are multiple processes involved in vibration relaxation, including the phonon-electron-phonon channel and the direct vibration of the molecule to phonon of the metal channel. It may be helpful to clarify your specific question for a more precise answer.
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thearif333
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How electron-hole pairs play its role in vibrational relaxation on a metal surface ?
When a molecule comes in contact with a metal surface, there are two channels which plays role in vibrational relaxation. One is Phonon channel and the second channel is electron-hole pairs in the metal. I googled it but can't find any literature to properly explain these two mechanism. Do anyone has any understanding of these relaxation processes ? Thanks
 
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Good evening,

You may also have some emission of photons from the molecule.

Your molecule interacts via Coulomb field with the surface and affects the electron-hole, yes. I think it may be named the Fano problem. It is however, not a dissipative channel.

Concerning the vibration relaxation, I would say that there are several processes.
- we have the phonon -> electron of the solid -> phonon of the metal channel;
- maybe vibration of the molecule -> phonon of the metal directly. But this I am less sure.

Maybe you can precise your question?

Best wishes,
Thibault
 

1. What is vibrational relaxation through electron-hole pairs?

Vibrational relaxation through electron-hole pairs is a process in which the excess energy of a molecule is dissipated through the creation of electron-hole pairs. This process occurs when a molecule is excited to a higher energy state and then rapidly returns to its original state by releasing energy in the form of heat or light.

2. How does vibrational relaxation through electron-hole pairs occur?

Vibrational relaxation through electron-hole pairs occurs when a molecule absorbs energy, such as from a laser or chemical reaction, and becomes excited to a higher energy state. The excess energy is then transferred to an electron, creating an electron-hole pair. The electron and hole then quickly recombine, releasing the excess energy in the form of heat or light.

3. What is the significance of vibrational relaxation through electron-hole pairs in scientific research?

Vibrational relaxation through electron-hole pairs is an important process in many areas of scientific research, particularly in the study of energy transfer and chemical reactions. It is also a key mechanism in technologies such as lasers and solar cells, where the efficient dissipation of excess energy is crucial.

4. What factors influence the rate of vibrational relaxation through electron-hole pairs?

The rate of vibrational relaxation through electron-hole pairs is influenced by several factors, including the energy of the excited state, the strength of the electron-hole interaction, and the availability of other energy dissipation pathways. Additionally, the properties of the surrounding environment, such as temperature and pressure, can also affect the rate of this process.

5. How is vibrational relaxation through electron-hole pairs studied in the laboratory?

In the laboratory, vibrational relaxation through electron-hole pairs is typically studied using techniques such as time-resolved spectroscopy, which allows researchers to track the energy transfer process in real-time. Additionally, computer simulations and theoretical models can also be used to study and understand the underlying mechanisms of this process.

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