Weinberg Lectures in QM (2013 Ed.), Equation 7.10.15

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The forum discussion centers on the derivation of the second-order derivative of the phase S, specifically ##\partial^2 S/\partial x_i \partial x_j##, as presented in Weinberg's "Lectures on Quantum Mechanics" (2013 Edition). The participants analyze the application of Schrödinger's equation, particularly Equation 7.10.13, and its implications for the Hamiltonian expansion around ##\nabla S##. The conversation highlights the necessity of understanding the product rule in calculus and the Wentzel-Kramers-Brillouin approximation to grasp the emergence of the second-order derivative in the context of quantum mechanics.

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jouvelot
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Hello everyone,
I don't get how the second-order derivative ##\partial^2 S/\partial x_i \partial x_j## of the phase S arrives here. If one performs a power series expansion of the Hamiltonian around ##\nabla S##, then I do get where the first term ##A## comes from, but then adding higher-order derivatives doesn't seem to introduce this second-order derivative of the phase S (even taking the somewhat
fuzzy footnote into account).
Does anyone who has read this book have an idea?
Thanks in advance.
Pierre
 
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To put my question in perspective, I put below an excerpt of the corresponding page (I hope small quotes are ok on the forum; if not, please feel fee to let me know) in Weinberg's book.

Schrödinger's equation 7.10.1 is ##H(p,x)\psi(x) = E \psi(x)##. The idea is to assume a solution ##\psi(x)= N(x)e^{-iS(x)\hbar}## (Equation 7.10.2), in which case, after identifying as usual ##p## with ##-i\hbar\nabla##, Schrödinger's equation is equivalent to Equation 7.10.13 below. Then, my question amounts to understanding the right part of Equation 7.10.15, and thus 7.10.14.

Thanks.

7.10.15.png
 
Last edited:
I'm not entirely sure I follow (7.10.13) (why p is identified with the expression containing grad S), but is it not simply the case that by acting on the product \psi = N e^{ i S} with two derivatives it's inevitable that you'll pull down a term that looks like the second derivative of S, just because of the product rule and the derivatives of exponentials?
 
One way to derive classical mechanics from quantum theory is to use singular perturbation theory, i.e., a formal expansion in powers of ##\hbar##, starting with the term ##\propto 1/\hbar## around ##\hbar=0##. In physics it's also known as the Wentzel-Kramers-Brillouin approximation. It's exactly the same technique how you derive ray optics from wave optics, i.e., the Maxwell equations. In leading order ##\mathcal{O}(1/\hbar)## you get the Hamilton-Jacoby partial differential equation for the "eikonal" ##S##, which is nothing else than the classical action, and that's equivalent to good old Newtonian mechanics.
 
Hi,

Thanks muppet for your message.

My understanding of Equation 7.10.13 is that it is the transcription of Schrödinger’s equation when applied to ##\psi## defined in terms of ##N(x)## and ##S(x)##.

The application of the operator ##p = -i\hbar\nabla## to such ##\psi## yields ##-i\hbar\nabla N(x) e^{iS(x)/\hbar}+N(x) \nabla S(x) e^{iS(x)/\hbar}##, which is equivalent to ##((-i\hbar\nabla + \nabla S(x) )N(x)) e^{iS(x)/\hbar}##. So since the phase exponential part of ##\psi## is kept unchanged, it can be factored out of the whole Schrödinger’s equation on ##\psi##, giving 7.10.13, which only applies to the ##N(x)## part of the wave function.

Now, if one performs a first-order power series expansion of the Hamiltonian at ##\nabla S(x)##, one gets the first parts of Equations 7.10.14 and 7.10.15, but I don’t see how to obtain the second parts even with higher-order expansions.

Thanks.

Pierre
 
Last edited:
Hi vanhees71,

Thanks for your comments, and I do remember reading about doing expansions in powers of ##\hbar##. But here, Weinberg speaks of orders of gradients, not of ##\hbar## (even though this is the same here, when dealing with the gradient of ##N(x)##). Given the book self-containedness up to now, I assume I should be able to derive this formula and see where the second-order derivatives of ##S## come from. But I don't see how.
 
Ok, going back to this after a small hiatus, I think I got it, and it's pretty simple in fact. Basically, from (7.10.13), one does a first-order expansion of H around ##\nabla S(x)##, yielding
$$H(\nabla S)N + (-i\hbar\sum_i\nabla_i)[(\partial H/\partial p_i)_{p=\nabla S} N] = E N.$$ The zero-th order terms ##H(\nabla S)N## and ##E N## cancel, as per (7.10.3). The remaining ##\nabla## yields then
$$ \sum_i(\partial H/\partial p_i)_{p=\nabla S} (\nabla_i N) + N\sum_{ij} (\partial p_j / \partial x_i)_{p=\nabla S} \partial/\partial p_j (\partial H/\partial p_i)_{p=\nabla S} = 0,$$
i.e., $$A.\nabla(N)+N {1\over 2}\sum_{ij} (\partial^2 S / \partial x_j\partial x_i) (\partial^2 H/\partial p_j\partial p_i)_{p=\nabla S} = A.\nabla(N)+NB = 0,$$
as in (7.10.14).
 
How to get 1/2 in your last equation ?
 
One needs the 1/2 prefactor since the term under the sum is symmetric in ##i## and ##j##, so one needs to counterbalance for the double counting. At least, this is how I make sense of it...
 

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