Weinberg Lectures on QM (2013 ed.), Equation 6.5.5

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The discussion centers on the derivation of Equation 6.5.5 from the Weinberg Lectures on Quantum Mechanics (2013 edition), specifically addressing the "overbar" notation used in correlation functions. The overline notation signifies an average over fluctuations, as clarified by a quote from the text. The derivation involves introducing a perturbation Hamiltonian matrix in an electric field, represented as $$H'_{nm}(t) = e \mathbf{x}_{nm}.\mathbf{E}$$, and establishing the relationship $$\overline{H'_{nm}(t_1)H'^*_{nm}(t_2)} = e^2 | \mathbf{x}_{nm} | ^2 f( t_1 - t_2)$$, which connects the average of the product of two Hamiltonians to the correlation function.

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jouvelot
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Hi everyone,

I'm a bit puzzled by the derivation of this formula, in particular since the definition of the "overbar" notation is a bit fuzzy (see Formula 6.4.1). Does anyone have a more formal definition of the correlation function in this setting (I know what a CF is, in general)? In this particular instance, I guess one just needs to consider the average of a product of 4 i.i.d. variables as a product of two averages of 2 i.i.d. variables to get the result. But I would have preferred a clearer definition of the notion involved. Any idea where to find a proper one?.

Thanks,

Pierre
 
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You might want to state these formulas explicitly for readers who don't have the boo.
 
Sure.

The overline notation is such that (quote from the book) "a line over a quantity indicates an average over fluctuations." Introduce a perturbation Hamiltonian matrix in an electric field ##\mathbf{E}## as (simplified) :
$$H'_{nm}(t) = e \mathbf{x}_{nm}.\mathbf{E}.$$
Now assume that
$$\overline{E_i(t_1)E_j(t_2)} = \delta_{ij}f( t_1 - t_2).$$
Then Equation 6.5.5 states that
$$\overline{H'_{nm}(t_1)H'^*_{nm}(t_2)} = e^2 | \mathbf{x}_{nm} | ^2 f( t_1 - t_2).$$
Even though it's somewhat intuitive, I was looking for a more formal definition of the "overline" notation and of its use here.
 

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