What are state functions in chemical thermodynamics?

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    Chemical Thermodynamics
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Discussion Overview

The discussion revolves around the concept of state functions in chemical thermodynamics, exploring definitions, examples, and the conditions under which certain variables are considered state functions. Participants express confusion and seek clarification on the topic.

Discussion Character

  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants express confusion about the definition of state functions, questioning whether a change in state necessarily implies a change in all state functions.
  • One participant attempts to clarify that state functions depend only on the current state of the system, providing examples such as gravitational potential energy, thermal energy, and enthalpy.
  • It is noted that certain quantities, like frictional energy, are not state functions because they depend on the path taken between two points.
  • Another participant requests a rewording of the initial confusion, suggesting that examples might help in understanding the concept better.
  • A later reply indicates that one participant has gained a clearer understanding of state functions after the explanations provided.

Areas of Agreement / Disagreement

Participants generally agree on the definition of state functions as being dependent on the current state of the system, but there is still some confusion regarding the implications of state changes and whether all state functions must change with a state change.

Contextual Notes

Some participants express uncertainty about the relationship between state changes and state functions, indicating a need for further clarification and examples to solidify understanding.

Karan Punjabi
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Guys I am getting confused that what is state function? People say if state changes then state function also changes. But my view is if that variable changes then only state changes and its not necessary when a state change will always lead to change of every state function.
 
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Karan Punjabi said:
Guys I am getting confused that what is state function? People say if state changes then state function also changes. But my view is if that variable changes then only state changes and its not necessary when a state change will always lead to change of every state function.
It is very hard to understand what you are saying. Can you please reword this in an alternate way? Maybe examples would help too.
 
I think I can explain state functions.
Things that are only dependent on the current state of the system are state functions.
Gravitational potential energy is a state function.It is determined by the position of the masses in your system.(On Earth the height above the ground.)
Thermal energy is a state function . Just knowing the temperature and the specific heat capacity you can figure it out.
Enthalpy is also a state function.It is dependent on the same things thermal energy depends and additionally on the volume and pressure of the system.
You can go on like this.Entropy and stuff like the other thermodynamic potentials are also a state function
The amount of frictional energy an object "loses" to the environment between two points is not only dependent on the two points.
It is not a state function because it depends on the path.

I suspect that did not help you much, but feel free to ask it again in a more specific way.
 
Tazerfish said:
I think I can explain state functions.
Things that are only dependent on the current state of the system are state functions.
Gravitational potential energy is a state function.It is determined by the position of the masses in your system.(On Earth the height above the ground.)
Thermal energy is a state function . Just knowing the temperature and the specific heat capacity you can figure it out.
Enthalpy is also a state function.It is dependent on the same things thermal energy depends and additionally on the volume and pressure of the system.
You can go on like this.Entropy and stuff like the other thermodynamic potentials are also a state function
The amount of frictional energy an object "loses" to the environment between two points is not only dependent on the two points.
It is not a state function because it depends on the path.

I suspect that did not help you much, but feel free to ask it again in a more specific way.
Yeah I understood about the state functions...now having a clear view to it...thank you
 

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