What are the energy differences between the atomic orbitals of He and He+?

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SUMMARY

The discussion focuses on the energy differences between the atomic orbitals of Helium (He) and Helium ion (He+). It establishes that in He, the 1s orbital has a lower energy due to electron shielding effects, which causes the 2s, 3s, and 3p orbitals to have higher energy levels compared to He+. In He+, with only one electron, the 1s orbital is more tightly bound due to the increased nuclear charge from two protons, resulting in a higher energy state for the 1s orbital compared to He's 1s2 configuration. The conversation also touches on the implications of shielding and the potential similarities between He and hydrogen in terms of energy levels.

PREREQUISITES
  • Understanding of atomic orbitals and their energy levels
  • Familiarity with the concept of electron shielding
  • Knowledge of the hydrogen-like atom model
  • Basic principles of quantum mechanics
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  • Study the effects of electron shielding in multi-electron atoms
  • Explore the concept of spin-orbit coupling in atomic physics
  • Investigate the energy level diagrams for hydrogen and hydrogen-like ions
  • Learn about the quantum mechanical treatment of atomic orbitals
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Students of quantum mechanics, physicists specializing in atomic structure, and educators teaching atomic theory will benefit from this discussion.

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Homework Statement


Compare the energies of the 1s, 2s, 3s and 3p orbitals for both the HE and He+. For He assume that one electron is always in the 1s orbital. State any other assumptions you have made


2. The attempt at a solution
I think:
He can be either 1s1 2s1 or 1s2
He+ has to be 1s1.

For He 1s2, the 1s orbital has a lower energy than in the case of He+ and since there is a greater shielding, this allows the 2s, 3s and 3p to rise in energy. Hence these have a higher energy than in He+.

For He1s1 2s1 is basically the same thing, only that now 1s1 has a higher energy than 1s2 but still lower than He+ and 2s1 has a lower energy than in the other cases.

Thanks!
 
Physics news on Phys.org
In He+, you have 2 protons attracting one electron.
Does this mean that the electron is more or less tightly bound to the nucleus?
Is "tightly bound" a lower or a higher energy?

If you are just using a shielding model, then isn't He going to be basically like hydrogen?

(Does your model include spin-orbit coupling?)
 

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