Energy level Diagram relating to SP3 hybridization

Join the discussion
Registration is free. Ask a follow-up in this thread, or start your own.
2 replies · 7K views
Physics345
Messages
250
Reaction score
23

Homework Statement



Experimental evidence suggests that the nitrogen atom in ammonia, NH3, has four identical orbitals in the shape of a pyramid or tetrahedron.

a) Draw an energy level diagram to show the formation of these hybrid orbitals.

(hint: No electron promotion is required)

b) Name the type of Hybrid orbitals found in NH3. Of the four hybrid orbitals on the N atom, how many will take part in bonding?

c)Draw for yourself the energy – level diagram showing the hybrid orbitals formed in the C atom when it bonds. Now look at those hybrid orbitals and those of the N atom, and describe how the bonding with a N atom will di²er with the bonding that occurs with a C atom, even though both atoms have four hybrid orbitals oriented in a tetrahedral shape

Homework Equations



None

The Attempt at a Solution


a)

KuUvJNv.png


KuUvJNv

b) sp^3 Is the hybrid orbital found in NH_3 in this case Nitrogen wants to complete its valence shell becoming like the noble gas Neon, thus it takes 3 electrons from each 1s orbital from the three hydrogen atoms and completes its 2p orbital forming a complete shell and a sp^3 hybridization. Therefore, it uses three hybrid orbitals.

c) The bonding with the nitrogen atom is different compared to the carbon atom. The carbon atom has 4 incomplete orbitals and only 2 electrons in its 2p orbitals while the third 2p orbital remains empty, while the nitrogen atom has 4 incomplete orbitals as well but the difference is that it has 3 electrons in each of its 2p orbitals.

IO7JmdG.png

I was just wondering if I did these correctly. Thanks in advance.
 

Attachments

  • IO7JmdG.png
    IO7JmdG.png
    5.5 KB · Views: 2,684
  • KuUvJNv.png
    KuUvJNv.png
    6.8 KB · Views: 6,934
Physics news on Phys.org
The explanation looks basically right. I would not label the individual hybrid orbitals as s and p. They would all be called sp3 orbitals, as they all contain some commbination of characteristics from s and p orbitals. So each hydrogen's 1s orbital mixes with one sp3-orbital (not a p-orbital) to form a N-H bond.

In answer (b), I would clarify that three sp3 orbital are used for bonding while the fourth sp3 orbital contains a lone pair (it is a non-bonding orbital).
 
  • Like
Likes   Reactions: Physics345
Based on your comments, I have rewrote my answers: Let me know what you think :)
p639acy.png

Ignore the attached file I accidentally posted that, now I can't figure out how to remove it, oh well.
 

Attachments

  • GstDhwh.png
    GstDhwh.png
    18.6 KB · Views: 1,192
  • p639acy.png
    p639acy.png
    26.9 KB · Views: 2,230
Last edited: