What Are the Momentum Characteristics of a Quantum Wave Packet?

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SUMMARY

The discussion revolves around the momentum characteristics of a quantum wave packet as presented in Liboff's "Introductory Quantum Mechanics" (2nd Edition), exercise 5.4. Participants analyze a scenario involving 1000 alpha particles in a defined state at t=0, with a wavefunction given by \(\psi (x,0)=\frac{1}{10}\exp (ik_ox)\) for \(|x|\leq 50cm\). Key calculations include determining the number of particles with momentum in the interval \(0\leq\hbar k\leq \hbar k_o\) and identifying momentum values where particles cannot be found. The discussion also addresses the preparation of such a state and the implications of Heisenberg's uncertainty principle.

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly wave functions and momentum operators.
  • Familiarity with Hilbert spaces and eigenfunctions in quantum mechanics.
  • Knowledge of Heisenberg's uncertainty principle and its mathematical implications.
  • Basic proficiency in integrals and their applications in quantum mechanics.
NEXT STEPS
  • Study the mathematical formulation of wave packets in quantum mechanics.
  • Learn about the implications of the uncertainty principle in quantum systems.
  • Research methods for preparing quantum states, including laser pulse techniques.
  • Explore the concept of momentum eigenstates and their role in quantum mechanics.
USEFUL FOR

This discussion is beneficial for students of quantum mechanics, particularly those preparing for advanced courses, as well as researchers and educators seeking to deepen their understanding of wave packet dynamics and momentum characteristics in quantum systems.

mgal95
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The problem stated below is from Liboff "Introductory Quantum Mechanics" (2nd Edition), exercise 5.4.

Homework Statement


A pulse ## 1m ## long contains ##1000 \alpha ## particles. At ## t=0## each ##\alpha## particle is in the state:
<br /> \psi (x,0)=\frac{1}{10}\exp (ik_ox)<br />
for |x|\leq 50cm and zero elsewhere. It is given that k_o=\pi/50
(a) At t=0, how many \alpha particles have momentum in the interval 0\leq\hbar k\leq \hbar k_o ?
(b) At which values of momentum will ##\alpha## particles not be found at ##t=0##?
(c) Describe an experiment to "prepare" such a state.
(d) Construct ##\Delta x## and ##\Delta p## for this state, formally. What is ##\Delta x\Delta p##? (Hint: To calculate ##\Delta p##, use ##|b(k)|^2##)

Homework Equations

The Attempt at a Solution


As I get it, we are in a Hilbert Space spanned by the eigenfunctions of the momentum operator, which constitute a continuous set. Thus, the state wavefunction should be written as:
<br /> \psi (x,0)=\int_{-\infty}^{+\infty} b(k)\phi_k dx<br />
where
<br /> \phi_k =\frac{1}{\sqrt{2\pi}}e^{ikx}<br />
Thus, we have (let L=100cm): ##\displaystyle b(k)=\int_{-\infty}^{+\infty}\psi (x,0)\phi^{\star}_k dx=...=\sqrt{\frac{2}{\pi L}}\frac{\sin[(k_o-k)L/2]}{k_o-k}##
(a) That being said, the number of particles in the given interval is just the integral:
<br /> N_{interval}=N_{total}\int_0^{k_o}|b(k)|^2dk<br />
(b) We will not find particles in the states whom ##b(k)## equals to zero, that is: ##\sin[(k_o-k)L/2]=0\rightarrow k=\frac{2n\pi}{L}-k_o\rightarrow p_k=\hbar k=\cdots## with ##n\in\mathbb Z##
(c) I suppose that we could get a laser beam of definite wavelength, which means of definitive momentum, and just send a pulse of ##100cm## in lenght. The state of such a laser beam (thought in the whole x axis) should be an eigenstate of the momentum (the one with ##k_o## should be chosen obviously). When we send the pulse (turn on and off the laser), we should get the given wavefunction. Is that any close to being right?
(d) I have encountered many problems here. I used the definition for the uncertainty, that is:
<br /> (\Delta p)^2=\left&lt;\hat{p}^2\right&gt;-\left&lt;\hat{p}\right&gt;^2=\left&lt;\psi \right|\hat{p}^2\left|\psi\right&gt;-\left&lt;\psi\right|\hat{p}\left|\psi\right&gt;^2<br />
Computing the above, I get:
##\displaystyle \left<\psi \right|\hat{p}^2\left|\psi\right>=\int_{-\infty}^{+\infty}\psi^{\star}\hat{p}^2\psi dx=(-i\hbar)^2(ik_o)^2\int_{-L/2}^{L/2}\psi^{\star}\psi dx=k_o^2\hbar^2##
And the other one: ##\displaystyle \left<\psi \right|\hat{p}\left|\psi\right>=\int_{-\infty}^{+\infty}\psi^{\star}\hat{p}\psi dx=(-i\hbar)(ik_o)\int_{-L/2}^{L/2}\psi^{\star}\psi dx=k_o\hbar##
But this gives ##\Delta p =0## ! This could be true if the uncertainty in ##x## was infinite. However, it is easily seen that this is not the case because: ##\displaystyle \left<x\right>=\int_{-L/2}^{L/2} x|\psi|^2dx=0## and ##\displaystyle \left<x^2\right>=\int_{-L/2}^{L/2} x^2|\psi|^2dx=\frac{L^2}{12}##
My first issue is that Heisenberg's uncertainty principle is violated, which means that somewhere lies a mistake. I see that the uncertainty in the momentum cannot be zero because I prooved in (a) that there is a continuous spectrum of the momentum eigenstates which constitute our wavefunction. In addition to that, I tried to compute the integrals in the case where the exponential is all over the x axis, namely when we have as state function an eigenstate of the momentum (where I should get zero uncertainty in the momentum). Both integrals (obviously) go to infinity and cannot be substracted. Last but not least, we are supposed to have ##C^{\infty}## functions as wavefunctions (at least ##C^2##). This postulate gives us the boundary conditions in problems like the infinite well. However ##e^z## does not equal zero for any ##z\in\mathbb C##. How can we have, then, such a wavefunction?
I want to know, first of all, which of my ideas are right and which are false. I study quantum mechanics on my own and there is no one else to ask for help. I am supposed to take the course at the University this Fall and I am trying to prepare myself a bit. I have a lot of other questions as well, but this one has got on my nerves for 2 days now and I cannot sleep, because I think I am deprived of basic knowledge.
Thank you for your time and forgive my english. It is not my mother tongue.
 
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mgal95 said:
I suppose that we could get a laser beam of definite wavelength, which means of definitive momentum, and just send a pulse of ##100cm## in lenght. The state of such a laser beam (thought in the whole x axis) should be an eigenstate of the momentum (the one with ##k_o## should be chosen obviously). When we send the pulse (turn on and off the laser), we should get the given wavefunction. Is that any close to being right?
In (a), you calculated that the beam is not monochromatic. It cannot be, otherwise it would extend to infinity. A true monochromatic source cannot send pulses.
There is no realistic way to get extremely sharp edges like here, but cutting a monochromatic beam from both sides from is probably the best approach.

(d): Your ψ is not differentiable at the ends of the beam. You cannot ignore that region, it leads to the deviations from your calculations. While it should be possible to use delta distributions here, it I guess it is easier to use the momentum spectrum that you found already.
 
Thank you very much for your reply! Sometimes I cannot see the obvious!
 

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