What Causes Quantum Energy Level Degeneracy?

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Homework Help Overview

The discussion revolves around the concept of quantum energy level degeneracy, particularly in the context of angular momentum and spin-orbit coupling. Participants explore the reasons behind the number of degenerate states associated with different energy levels, specifically for the case of l=1 and its corresponding j values.

Discussion Character

  • Exploratory, Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants discuss the relationship between quantum numbers j, l, and m, and how these relate to the splitting of energy levels. Questions arise regarding the distribution of degenerate states among different j values and the implications of external magnetic fields on these states.

Discussion Status

Some participants have provided insights into the role of spin-orbit coupling in energy level splitting, while others express confusion about the specific distribution of states and the concept of weak Zeeman splitting. The conversation reflects a mix of understanding and uncertainty, with various interpretations being explored.

Contextual Notes

Participants are navigating complex quantum mechanics concepts without a specific homework question, which may influence the depth of their inquiries and the clarity of their assumptions. The mention of weak Zeeman splitting introduces additional complexity that is not fully resolved in the discussion.

soxymoron
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I'm not going to follow the form because this is more of a hand-wavy question, I don't need it for a specific homework question but it's confusing me, I hope it's still okay to post here.

I understand the splitting of energy levels due to j (dependent on l and s) and I understand that each of the split states contains multiple degenerate states. What I don't understand is where they come from.

For an example of l=1 the energy is split into a j=1/2 and a j=3/2 levels. I know 6 states in total are contain within this split 2:4. This is the bit I don't understand, I'm assuming that the degenerate states are caused by the quantum number m but if that's the case why aren't they split evenly 3 to each energy level?

Thanks for any help you can give me
 
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It's because the interaction that splits the energies of the state is the spin-orbit coupling, proportional to [tex]\vec{L}\cdot\vec{S}[/tex], which can be rewritten as being proportional to the difference [tex]\vec{J}^2-\vec{L}^2-\vec{S}^2[/tex], which is dependent only on the quantum numbers j and l (s=1/2 in either case): so that's why the l=1 levels split according to their j quantum number, and not m.

In a magnetic field, on the other hand, the additional splitting would depend on m.
 
right... but i f you want to go deeper... see the rapresentations of angular momentu in QM, see what are the wieight of a reprs ;)
 
Okay so m only comes into play when a magnetic field is added, that makes sense. Though I'm still not sure why j=1/2 contains 2 degenerate states and j=3/2 contains 4. Also, I have a question which asks me to 'estimate the weak Zeeman splitting of a system', my main problem with that is I'm not sure what the weak Zeeman splitting of a system is. I could calculate it for each state but I don't know what that would mean for the whole thing.
 
For j=1/2 there are two states: m=+/- 1/2, and for j=3/2 there are 4 different m-states.

The "weak" Zeeman effect just refers to a situation where the energy shift due to the magnetic field is small and can be treated with perturbation theory: the unperturbed Hamiltonian has split the l=1 level into 2: j=1/2 and j=3/2, and then the Zeeman effect splits each of those into 2 and 4, respectively, different energy levels.
 

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