What causes the difference in reactivity between alkali metals?

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SUMMARY

The discussion centers on the reactivity differences among alkali metals, specifically focusing on lithium, sodium, potassium, rubidium, and cesium. It is established that as one moves down the periodic table, the size of the ions increases and ionization energies decrease, making reactions easier with larger alkali metals. The perceived "huge jump" in reactivity between potassium (K) and rubidium (Rb) is clarified as a threshold effect in energy release rates. Under specific conditions, such as exposure to hot air or higher oxygen concentrations, potassium can exhibit reactivity similar to rubidium.

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Calpalned
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We know that lithium, sodium and potassium tarnish when exposed to air, but rubidium and cesium catch on fire. Why is there such a huge jump in reactivity between Rb and K?
 
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Good question. Because going down in the periodic system, the ions get bigger and bigger, ionization energies become smaller. So it's easier to start a reaction with the bigger guys.
Does that make it clearer ?
 
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BvU has it right. There's not really a "huge jump" in reactivity ... it's just a matter of reaching a threshold in the rate of energy release, to a point where things proceed differently. Expose K to hot air, or to a higher concentration of oxygen, and it will behave like Rb.
 
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