What do the blue and pink color of the rust indicator shown mean?

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SUMMARY

The discussion clarifies the meaning of blue and pink colors in a rust indicator composed of potassium hexacyanoferrate(III) and phenolphthalein. The blue color indicates the presence of Fe2+ ions, confirming that rusting has already occurred. Conversely, the pink color signifies the presence of hydroxide ions, suggesting that rust formation is imminent but not yet complete. The participants agree that both ions are produced simultaneously, reflecting different half-reactions in the rusting process.

PREREQUISITES
  • Understanding of redox reactions
  • Knowledge of chemical indicators, specifically phenolphthalein
  • Familiarity with iron corrosion processes
  • Basic chemistry of ions, particularly Fe2+ and hydroxide ions
NEXT STEPS
  • Research the electrochemical processes involved in iron rusting
  • Study the role of potassium hexacyanoferrate(III) as a chemical indicator
  • Learn about the formation and detection of hydroxide ions in aqueous solutions
  • Explore the implications of rusting on metal integrity and prevention methods
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Chemistry students, materials scientists, and professionals involved in corrosion prevention and metal treatment will benefit from this discussion.

Green18
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Hello, everyone.
What do the blue and pink color the rust indicator shown mean?

Let say, the mixture of potassium hexacyanoferrate(III) and phenolphthalein is the rust indicator. And we use to detect the rusting of an iron nail. And the result is: the tip, head region of the nail appear blue color; the straight region appears pink color.
Is that the blue region shows Fe2+ ions formed? And, the pink shows hydrogen ions present?

But, even it shows these ions are present, what does it mean? The blue area is rusting? And the pink area no rusting?

Confused :( please help!
 
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Green18 said:
Is that the blue region shows Fe2+ ions formed?

Yes.

And, the pink shows hydrogen ions present?

No, quite the opposite - it shows where the amount of H+ is small.

But, even it shows these ions are present, what does it mean?

Where do they come from?
 
Thanks for replying.
Sorry, my bad. That is a typo.
I should write 'hydroxide ions' ,
the pink area shows the presence of HYDROXIDE ions .
But, i don't get it, even hydroxide ions is produced, what does it mean? Does it mean the pink area part is rusting?
 
Last edited:
No, it contains possible rusting product.
 
Borek said:
No, it contains possible rusting product.

Thanks again.
So simply speaking, the blue area means the rusting has already taken place/ the rust is formed . And the pink area means it is going to form rust (coz hydroxide ions are produced before rust is formed.)
Am i right? :)
 
I think both ions are produced at the same time, they just show where different half reactions occur (they don't have to go in the same place, as long as there is conductor present).
 
Borek said:
I think both ions are produced at the same time, they just show where different half reactions occur (they don't have to go in the same place, as long as there is conductor present).
Thank you
 

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